| 68078-25-1

• CAS: 68078-25-1
• 化学式: ArN
• 分子量: 53.9547
• InChiKey: ZWZARVZKFFSYBA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.48
• 重原子数：
  2.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  22.3
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  氮 、 氩 以 gas 为溶剂， 生成 argon dimer 、 Argon Nitrogen Nitrogen 、 argon 、
  参考文献：
  名称：

  Electron beam fluorescence spectrometry of internal state populations in nozzle beams of nitrogen and nitrogen/rare gas mixtures

  摘要：

  Rotational level populations of N2 were measured downstream from the skimmer in beams of pure N2 and in mixtures of N2 with He, Ne, and Ar expanded from room temperature nozzles. The range of p0D was from 5 to 50 Torr cm. The formation of dimers and higher condensates of beam species was monitored during the runs. The effect of condensation energy release on rotational populations and parallel temperatures was readily observed. Two different methods for evaluating the rotational population distributions were compared. One method is based on a dipole-excitation model and the other on an excitation matrix obtained empirically. Neither method proved clearly superior. Both methods indicated nonequilibrium rotational populations for all of our room temperature nozzle expansion conditions. Much of the nonequilibrium character appears to be due to the behavior of the K = 2 and K = 4 levels, which may be accounted for in terms of the rotational energy level spacing. In particular, the overpopulation of the K = 4 level is explained by a near-resonant transfer of rotational energy between molecules in the K = 6 and K = 0 states, to give two molecules in the K = 4 state. Rotational and vibrational temperatures were determined for pure N2 beams from nozzles heated up to 1700 °K. The heated nozzle experiments indicated a 40% increase in the rotational collision number between 300 and 1700 °K.

  DOI：

  10.1063/1.442103