(3,3'-dicarbomethoxy-2,2'-bipyridyl)dichloropalladium(II) | 188860-22-2

• 英文名称: (3,3'-dicarbomethoxy-2,2'-bipyridyl)dichloropalladium(II)
• CAS: 188860-22-2
• 化学式: C₁₄H₁₂Cl₂N₂O₄Pd
• 分子量: 449.586
• InChiKey: JHWJIKQLGUPGFJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (3,3'-dicarbomethoxy-2,2'-bipyridyl)dichloropalladium(II) 、 二氯甲烷 、 2-(3-甲氧基羰基吡啶-2-基)吡啶-3-甲酸甲酯 、 四(3,5-二(三氟甲基)苯基)硼酸钠 反应 3.0h， 以64%的产率得到
  参考文献：
  名称：

  Pd(II) complexes with 3,3′-substituted bipyridine ligands: Synthesis, crystal structure, DFT calculations and catalytic studies in compressed carbon dioxide

  摘要：

  Cationic bis(chelated) complexes [Pd(N-N)(2)][BArF](2) with N-N = 3,3'-diester-2,2'-bipyridine ligands were prepared and tested as catalyst for the CO/tert-butylstyrene copolymerization using compressed carbon dioxide as a solvent. The NMR analysis of these complexes suggests the formation of several species in solution. A detailed DFT calculation analysis indicated that these species correspond to different relative orientations of the carbonyl group. These complexes showed poor catalytic activity towards the formation of polyketones, producing only poly(tert-butylstyrene) when trifluoroethanol was used as a solvent. The use of compressed carbon dioxide favored the formation of the polyketones when the complexes with methyl and isopropyl ester derivatives were employed as catalysts. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.09.053
• 作为产物：
  描述：

  potassium tetrachloropalladate(II) 、 2-(3-甲氧基羰基吡啶-2-基)吡啶-3-甲酸甲酯 以 乙醇 、 水 为溶剂， 生成 (3,3'-dicarbomethoxy-2,2'-bipyridyl)dichloropalladium(II)
  参考文献：
  名称：

  3,3′-Dicarbomethoxy-2,2′-bipyridyl complexes of palladium(II), platinum(II) and rhodium(III)

  摘要：

  DOI：

  10.1016/s0277-5387(00)87028-x