tetrahydrofuran-[5-D]-3-methyl-1-boraadamantane | 1167417-92-6

• 英文名称: tetrahydrofuran-[5-D]-3-methyl-1-boraadamantane
• CAS: 1167417-92-6
• 化学式: C₁₄H₂₅BO
• 分子量: 221.155
• InChiKey: OLEAEBQBLGSJJO-UQBWLURTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  3-氯吡啶 、 tetrahydrofuran-[5-D]-3-methyl-1-boraadamantane 以 正戊烷 为溶剂， 反应 0.5h， 以72%的产率得到3-chloropyridine-[5-D]-3-methyl-1-boraadamantane
  参考文献：
  名称：

  Design of Bicyclic and Cage Boron Compounds Based on Allylboration of Acetylenes with Allyldichloroboranes

  摘要：

  Allylboration of acetylenes with allyldichloroboranes has been proposed as a first step of allyl boron-acetylene condensation and a way to design condensation products from stage to stage. The chemistry has been applied to the synthesis of isomeric 3-borabicyclo[3.3.1]non-6-enes transformed into 3-methyl-1-boraadamantane and [5-D]-3-methyl-1-boraadamantane derivatives.

  DOI：

  10.1021/ol900793r
• 作为产物：
  描述：

  borane-d3-tetrahydrofuran 、 1,3-dimethyl-7-methylene-3-borabicyclo[3.3.1]nonane 以 四氢呋喃 为溶剂， 反应 3.0h， 以90%的产率得到tetrahydrofuran-[5-D]-3-methyl-1-boraadamantane
  参考文献：
  名称：

  Design of Bicyclic and Cage Boron Compounds Based on Allylboration of Acetylenes with Allyldichloroboranes

  摘要：

  Allylboration of acetylenes with allyldichloroboranes has been proposed as a first step of allyl boron-acetylene condensation and a way to design condensation products from stage to stage. The chemistry has been applied to the synthesis of isomeric 3-borabicyclo[3.3.1]non-6-enes transformed into 3-methyl-1-boraadamantane and [5-D]-3-methyl-1-boraadamantane derivatives.

  DOI：

  10.1021/ol900793r