| 1020152-69-5

• CAS: 1020152-69-5
• 化学式: C₁₉H₁₉Cl₂CoN₃
• 分子量: 419.279
• InChiKey: PJCJVANPCOXTRK-TXBTUDEPSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  6-甲基-2-吡啶甲醛 、 8-amino-2-isopropylquinoline 、 cobalt(II) chloride 以 溶剂黄146 为溶剂， 以79.7%的产率得到
  参考文献：
  名称：

  Iron(II) and cobalt(II) complexes bearing N-((pyridin-2-yl)methylene)-quinolin-8-amine derivatives: Synthesis and application to ethylene oligomerization

  摘要：

  A series of tridentate N boolean AND N boolean AND N iron(II) and cobalt(II) complexes containing N-((pyridin-2-yl) methylene)-quinolin-8-amine derivatives were synthesized and characterized by elemental and spectroscopic analyses. The molecular structure of 1a was con. rmed by X-ray diffraction analyses. On treatment with modified methylaluminoxane, these metal complexes exhibited good catalytic activities up to 2.8 x 10(6) g mol(-1)(Fe) h(-1) for ethylene oligomerization, and butenes were the major products with nice selectivity for 1-C-4. The steric and electronic effects on catalytic activities of metal complexes were carefully investigated as well as the influence of various reaction parameters. In the catalytic system, Fe(II) complexes performed better catalytic activities than their Co(II) analogues. With ligands having bulky substituents, the better catalytic activity was observed in catalytic system of Fe(II) complex, however, the lower catalytic activity was obtained in catalytic system of Co(II) complexes. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.12.030