Ru(CCCCCu)(dppe)(η5-C5Me5) | 1234333-69-7

• 英文名称: Ru(CCCCCu)(dppe)(η5-C5Me5)
• 英文别名: Ru(CCCCCu)(dppe)Cp*
• CAS: 1234333-69-7
• 化学式: C₄₀H₃₉CuP₂Ru
• 分子量: 746.313
• InChiKey: HHWQHARWLPAETO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {(copper)2(μ-bis(diphenylphosphino)methane)2(MeCN)2}{BF4}2 、 Ru(CCCCCu)(dppe)(η5-C5Me5) 以 甲醇 、 二氯甲烷 为溶剂， 以77%的产率得到[Cu6(CCCC[Ru(dppe)(η5-C5Me5)])4(dppm)2](BF4)2
  参考文献：
  名称：

  Preparation and molecular structures of the decanuclear diynyl-ruthenium-silver and -copper complexes [M6{μ3-CCCC[Ru(dppe)Cp∗]}4(μ-dppm)2](BF4)2 (M=Ag, Cu)

  摘要：

  Reactions between [M-2(dppm)(2)(NCMe)(2)]X-2 [M = Ag, X = ClO4; M = Cu, X = BF4] and Ru(C CC CM)(dp-pe)Cp* [M = Ag, Cu; generated in situ from Ru(C CC CH)(dppe)Cp* and AgNO3 or CuCl(PPh3), respectively] afford the cationic mixed-metal cluster diynyl complexes [M-6{mu(3)-C CC C[Ru(dppe)Cp*]}(4)(mu-dppm)(2)]X-2, of which the structures were determined by single-crystal XRD studies. Electrochemical studies indicate that there is no interaction between the ruthenium centres. Reactions between [M-2(mu-dppm)(2)(NCMe)(2)](BF4)(2) and Ru(C CC CM')(dppe)Cp* (M,M' = Cu, Ag) afforded a mixture of Ag-6 Cu-n(n) clusters, as shown by ES-MS and crystallographic studies. Preliminary studies suggest that extensive dis-proportionation occurs in solution. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.03.016
• 作为产物：
  描述：

  (triphenylphosphine)CuCl 、 Ru(C≡CC≡CSiMe3)(dppe)Cp* 在 NaOMe 作用下， 以 四氢呋喃 为溶剂， 以73%的产率得到Ru(CCCCCu)(dppe)(η5-C5Me5)
  参考文献：
  名称：

  Preparation and molecular structures of the decanuclear diynyl-ruthenium-silver and -copper complexes [M6{μ3-CCCC[Ru(dppe)Cp∗]}4(μ-dppm)2](BF4)2 (M=Ag, Cu)

  摘要：

  Reactions between [M-2(dppm)(2)(NCMe)(2)]X-2 [M = Ag, X = ClO4; M = Cu, X = BF4] and Ru(C CC CM)(dp-pe)Cp* [M = Ag, Cu; generated in situ from Ru(C CC CH)(dppe)Cp* and AgNO3 or CuCl(PPh3), respectively] afford the cationic mixed-metal cluster diynyl complexes [M-6{mu(3)-C CC C[Ru(dppe)Cp*]}(4)(mu-dppm)(2)]X-2, of which the structures were determined by single-crystal XRD studies. Electrochemical studies indicate that there is no interaction between the ruthenium centres. Reactions between [M-2(mu-dppm)(2)(NCMe)(2)](BF4)(2) and Ru(C CC CM')(dppe)Cp* (M,M' = Cu, Ag) afforded a mixture of Ag-6 Cu-n(n) clusters, as shown by ES-MS and crystallographic studies. Preliminary studies suggest that extensive dis-proportionation occurs in solution. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.03.016