[(N-methyl-pyridylmethylideneamino)ZnCl2] | 127796-48-9

• 英文名称: [(N-methyl-pyridylmethylideneamino)ZnCl2]
• CAS: 127796-48-9
• 化学式: C₇H₈Cl₂N₂Zn
• 分子量: 256.45
• InChiKey: OZIPHSOMARCYCO-LGSAIMRHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-(2-pyridylmethylene)methylamine 、 zinc(II) chloride 以 四氢呋喃 为溶剂， 生成 [(N-methyl-pyridylmethylideneamino)ZnCl2] 、 [(N-methyl-pyridylmethylideneamino)ZnCl2]2
  参考文献：
  名称：

  Synthesis and structural diversity of 2-pyridylmethylideneamine complexes of zinc(II) chloride

  摘要：

  The addition reactions of zinc(II) chloride to N-substituted pyridine-2-carbaldimines [Py-CH=NR, R = Me (1a), Ph (1b), Bz (1c), allyl (1d)] lead to different complexes dependent on the N-bound substituent R. The 1:1 complexes show molecular structures of the type [(Py-CH=NR) ZnCl2] for R = methyl (2a), phenyl (2b), and allyl (2d) with a distorted tetrahedral environment for the zinc atom. The zinc complex with the N-methylated pyridine-2-carbaldimine also forms a dimer of the type [(Py-CH=NR)ZnCl2](2) (2a)(2) with a square pyramidal coordination sphere of zinc. A 3: 2 stoichiometry is observed for R = benzyl and an ion pair of the type [Zn(Py-CH=NR)(3)](2+) [ZnCl4](2) (2c) is found in the solid state. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.06.044