Convenient Synthesis of [Et4N]2[M2(CO)8(μ-H)2] (M = Mo, W)
摘要:
[Et4N](2)[W-2(CO)(8)(mu-H)(2)] and [Et4N](2)[Mo-2(CO)(8)(mu-H)(2)] were synthesized in 47 and 31% yields, respectively, from the reaction of (TMED)M(CO)(4) (M = Mo, W; TMED = N,N,N',N'-tetramethylethylelzediamine) with a stoichiometric quantity of [Et4N][BH4].
Convenient Synthesis of [Et4N]2[M2(CO)8(μ-H)2] (M = Mo, W)
摘要:
[Et4N](2)[W-2(CO)(8)(mu-H)(2)] and [Et4N](2)[Mo-2(CO)(8)(mu-H)(2)] were synthesized in 47 and 31% yields, respectively, from the reaction of (TMED)M(CO)(4) (M = Mo, W; TMED = N,N,N',N'-tetramethylethylelzediamine) with a stoichiometric quantity of [Et4N][BH4].
Highly reduced organometallics. 9. Synthesis and characterization of the tetrasodium tetracarbonylmetalates(4-) of chromium, molybdenum, and tungsten, Na4M(CO)4: their reactions with weak acids to generate H2M2(CO)82-(M = Cr, Mo, and W)