[(η5-cyclopentadienyl)Co(2,3-di(n-butyl)-4,5-di(n-propyl)cyclopentadienone)] | 1014688-66-4

• 英文名称: [(η5-cyclopentadienyl)Co(2,3-di(n-butyl)-4,5-di(n-propyl)cyclopentadienone)]
• 英文别名: [CoCp(2,3-di(n-butyl)-4,5-di(n-propyl)cyclopentadienone)]
• CAS: 1014688-66-4
• 化学式: C₂₄H₃₇CoO
• 分子量: 400.55
• InChiKey: FDPYUKLDOBUEDC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  carbon monoxide,cobalt,cyclopenta-1,3-diene 、 4-辛炔 、 2,3-dibutylcyclopropenone 以 further solvent(s) 为溶剂， 以32%的产率得到[(η5-cyclopentadienyl)Co(2,3-di(n-butyl)-5,6-di(n-propyl)-p-benzoquinone)]
  参考文献：
  名称：

  CpCo-Mediated Reactions of Cyclopropenones: Access to CpCo-Capped Benzoquinone Complexes

  摘要：

  The reaction of di(n-propyl)cyclopropenone (7), di(n-butyl)cyclopropenone (16), and bicyclo[12.1.0]pentadeca-1(14)-en-7-yn-15-one (21) with CpCo(CO)(2) and CpCo(cod) yielded CpCo-complexed benzoquinone and cyclopentadienone derivatives. When 16 was reacted with CPCO(CO)(2) and a 10-fold surplus of 4-octyne, a mixture of CpCo-capped benzoquinone 25 and cyclopentadienone 26 was isolated. The reaction of cyclopropenone 16 containing a C-13-labeled CO group with CPCO(CO)(2) yielded a CpCo-capped tetrakis(n-butyl)-p-benzoquinone with one C-13 nucleus per molecule as the main product. The mechanism of the formation of p-benzoquinone is discussed on the basis of the results of trapping and labeling experiments.

  DOI：

  10.1021/om701115w