| 232921-06-1

• CAS: 232921-06-1
• 化学式: C₁₄H₁₃CrNO₃
• 分子量: 295.258
• InChiKey: LTRNUCJLDHCZKL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 synthetic air 作用下， 以 neat (no solvent) 为溶剂， 生成 chromium(III) oxide
  参考文献：
  名称：

  Thermal decomposition of homo- and heterometallic (η6-arene)tricarbonylchromium derivatives

  摘要：

  The thermal decomposition of homo- and heterometallic (eta(6)-arene)tricarbonylchromium complexes in dry air has been investigated by thermogravimetric analysis. The final decomposition products are characterized by X-ray powder diffractometry which confirms the formation of Cr2O3, PdO and Co2CrO4 (C) 1999 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0040-6031(99)00079-9
• 作为产物：
  描述：

  1-二甲基胺-2-丙炔 、 tricarbonyl(η6-chlorobenzene)chromium 、 bis-triphenylphosphine-palladium(II) chloride 在 CuI 、 NEt₃ 作用下， 以 四氢呋喃 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthesis and Reactivity of (η⁶-arene)tricarbonylchromium Compounds Incorporating Propargylamine Units. X-ray Crystal Structures of YCH₂C⋮CPh[Cr(CO)₃] (Y = NMe₂, N(Me)(CH₂Ph)) and {Pd-trans-C[(Ph)Cr(CO)₃]C(Cl)CH₂NMe₂(Cl)(Py)}

  摘要：

  The syntheses, structures, and reactivities of new (eta(6)-arene)tricarbonylchromium compounds bearing propargylamines are described. The reaction of (eta(6)-C6H5Cl)tricarbonylchromium with propargylamines affords YCH(R)C=CPh[Cr(CO)(3)] (1a, R = H, Y = NMe2; 1b, R = Me, Y = NMe2; 1c, R = H, Y = N(Me)(CH2Ph)) in good yield. The reaction of 1a,b with Li2PdCl4 generates the air-stable dimeric compounds (Pd-trans-C[(Ph)Cr(CO)(3)]=C(Cl)CH(R)NMe2(mu-Cl)}(2) (2a, R = H; 2b, R = Me), which can be converted to a monomeric and soluble species (Pd-trans-C[(Ph)Cr(Co)(3)]=C(Cl)CH(R)NMe2(Cl)(Py)} (3a, R = H; 8b, R = Me) after reaction with pyridine. Compounds 1a, 1c, and 3a were structurally characterized by single-crystal X-ray diffraction studies.

  DOI：

  10.1021/om990231i

文献信息

• Casagrande O.L.; Gomes; Dupont, Journal of the Chemical Society, Dalton Transactions, 2001, # 10, p. 1634 - 1638
  作者：Casagrande O.L.、Gomes、Dupont、Burrow、Lough

  DOI：——

  日期：——