| 181534-89-4

• CAS: 181534-89-4；196007-02-0
• 化学式: C₃₀H₃₀Cr₂Ni₂O₁₀P₂
• 分子量: 833.882
• InChiKey: VWYCMUJFDJOROA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  以 四氢呋喃 为溶剂， 生成 、 {(η5-C5Me5)Ni(P3)(Cr(CO)5)3} 、
  参考文献：
  名称：

  Zur Transformation des P ₄ ‐Tetraeders durch Ni‐Komplexe

  摘要：

  The Transformation Pathway of the P4Tetrahedron by Ni ComplexesThe thermal reaction of [Cp*NiCO]2with white phosphorus in the presence of [Cr(CO)5(thf)] at 70°C produces the bentcyclo‐P4ligand complex4and the Ni2P4prismane5. However under photochemical conditions additional products such ascyclo‐P3complexes6and the Ni2P2tetrahedrane7are also formed.4and5were characterized by NMR, IR, and mass spectroscopy as well as by X‐ray structure analysis. The structures of these products and the experimentals verification of the conversion of4into5or into6and7as well as the cubane analog12gives evidence for a transformation pathway starting from P4tetrahedron via a possible bicyclotetraphosphane intermediate to give the bent P4complex4. From4several pathways are possible; the main route is to form the Ni2P4prismane5. Photochemically a P3/P1fragmentation also occurs, albeit in low yield, to give5and6.

  DOI：

  10.1002/cber.19961291026

文献信息

• Scheer, Manfred; Schuster, Kay; Krug, Andre, Chemische Berichte, 1996, vol. 129, # 8, p. 973 - 979
  作者：Scheer, Manfred、Schuster, Kay、Krug, Andre、Hartung, Helmut

  DOI：——

  日期：——
• [CR(CO) ₅ PCl ₃ ] — A Starting Material for Phosphorus‐Rich P _x Ligand Complexes
  作者：Manfred Scheer、Kay Schuster、André Krug、Helmut Hartung

  DOI：10.1002/cber.19971300919

  日期：1997.9

  Abstract[Cr(CO)5PCl3] reacts with different metallates K[CpxMo(CO)3] [Cpx = ·5‐C5H4tBu (Cp]), ·5‐C5H3tBu2‐1,3 (Cp))], K[CpFe(CO)2], K[Cp]Cr(CO)3], K[C}*Ni(CO)] and Na2[Cr2(CO)10] at –78°C in THF to yiel various P2, cyclo‐ P3 and cyclo‐P5 ligand complexes of the formulae [Cp] Mo(CO)2 (.2‐P3)] (1a), [Cp]Mo(CO)2(.3‐P3)] (1b), [CP'Mo‐(CO)2}2(μ,.2‐P2)] (2a), [Cp]Mo(CO)2}2(μ, ·2‐P2)] (2b), [Cp]Fe).5‐P5)] (3), [(Cp'Cr)2(μ,.5‐P5)] (4), [Cp]Cr(CO)2}2‐(μ,.2‐P2)] (5), [(Cp*Ni)2(μ,.2‐P2)Cr(CO)5}2] (6). [(CO)5Cr}Cl2PPCl2Cr(CO)5}] (7) and [Cr(CO)5}2PCl (8). Comprehensive studies of the reaction pathway leading to formation of the cyclo‐P3 product 1a give strong indications that a sequence involving metal‐halogen exchange and stepwise P–P bond formation takes place, proceeding via [CO}5Cr}Cl2PPCl2Cr(CO)5}] (7) and the cyclo‐P3 precursor compond [Cp]Mo(CO)3}Cp'Mo(CO)2}2Cr(CO)5}(μ,.3:1:1−P3)] (9). The latter two complexes have been isolated and structurally characterized.