{(η5-C5Me5)Ni(P3)(Cr(CO)5)3} | 123775-65-5

• 英文名称: {(η5-C5Me5)Ni(P3)(Cr(CO)5)3}
• CAS: 123775-65-5
• 化学式: C₂₅H₁₅Cr₃NiO₁₅P₃
• 分子量: 862.984
• InChiKey: ZBYBCUGLHFPOFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  {(η5-C5Me5)Ni(η3-P3)} 、 六羰基铬 在 THF 作用下， 以 四氢呋喃 为溶剂， 以43%的产率得到{(η5-C5Me5)Ni(P3)(Cr(CO)5)3}
  参考文献：
  名称：

  Scherer, Otto J.; Braun, Juergen; Wolmershaeuser, Gotthelf, Chemische Berichte, 1990, vol. 123, p. 471 - 476

  摘要：

  DOI：

文献信息

• Zur Transformation des P ₄ ‐Tetraeders durch Ni‐Komplexe
  作者：Manfred Scheer、Uta Becker

  DOI：10.1002/cber.19961291026

  日期：1996.10

  The Transformation Pathway of the P4Tetrahedron by Ni ComplexesThe thermal reaction of [Cp*NiCO]2with white phosphorus in the presence of [Cr(CO)5(thf)] at 70°C produces the bentcyclo‐P4ligand complex4and the Ni2P4prismane5. However under photochemical conditions additional products such ascyclo‐P3complexes6and the Ni2P2tetrahedrane7are also formed.4and5were characterized by NMR, IR, and mass spectroscopy as well as by X‐ray structure analysis. The structures of these products and the experimentals verification of the conversion of4into5or into6and7as well as the cubane analog12gives evidence for a transformation pathway starting from P4tetrahedron via a possible bicyclotetraphosphane intermediate to give the bent P4complex4. From4several pathways are possible; the main route is to form the Ni2P4prismane5. Photochemically a P3/P1fragmentation also occurs, albeit in low yield, to give5and6.