[Mo(CO)4(Ph2PCMe(allyl)PPh2)] | 1001401-09-7

• 英文名称: [Mo(CO)4(Ph2PCMe(allyl)PPh2)]
• CAS: 1001401-09-7
• 化学式: C₃₃H₂₈MoO₄P₂
• 分子量: 646.47
• InChiKey: KRNCDERKCKUGMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tetracarbonyl-bis(diphenylphosphino)methane-molybdenum(0) 在 n-C₄H₉Li 作用下， 以 四氢呋喃 为溶剂， 生成 [Mo(CO)4(Ph2PCMe(allyl)PPh2)]
  参考文献：
  名称：

  Backbone modified small bite-angle diphosphines: Synthesis and molecular structures of [M(CO)4{X2PC(R1R2)PX2}] (M=Mo, W; X=Ph, Cy; R1=H, Me, Et, Pr, allyl, R2=Me, allyl)

  摘要：

  A range of new small bite-angle diphosphine complexes, [M(CO)(4) {X2PC((RR2)-R-1)PX2}] (M = Mo, W; X = Ph, Cy; R-1 = H, Me, Et, Pr, allyl, R 2 = Me, allyl), have been prepared via elaboration of the methylene backbones in [M(CO)(4)(X2PCH2PX2)] as a result of successive deprotonation and alkyl halide addition. When X = Ph it proved possible to replace both methylene protons but for X = Cy only one substitution proved possible. This is likely due to the electron-releasing nature of the cyclohexyl groups but may also be due to steric constraints. Attempts to prepare the bis(allyl) substituted complex [Mo(CO)(4){Ph2PC(allyl)(2)PPh2}] were only moderately successful. The crystal structures of nine of these complexes are presented. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.09.024