[Ru(bpyBr)2(acac)][PF6] | 1228260-41-0

• 英文名称: [Ru(bpyBr)2(acac)][PF6]
• 英文别名: [Ru(4-bromo-2,2'-bipyridine)2(acetylacetone(-H))][PF6]
• CAS: 1228260-41-0
• 化学式: C₂₅H₂₁Br₂N₄O₂Ru*F₆P
• 分子量: 815.31
• InChiKey: ORJXBSYCLWPXHH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(bpyBr)2(acac)][PF6] 、 2-甲基-3-丁炔-2-醇 在 Cu/Pd(PPh₃)4 catalyst 作用下， 以 dimethylformamide 、 further solvent(s) 为溶剂， 以76%的产率得到[Ru(bpyOH)2(acac)][PF6]
  参考文献：
  名称：

  Synthesis and characterization of β-diketonato ruthenium(II) complexes with two 4-bromo or protected 4-ethynyl-2,2′-bipyridine ligands

  摘要：

  Two new mononuclear mixed-ligand ruthenium(II) complexes with acetylacetonate ion (2,4-pentanedionate, acac) and functionalized bipyridine (bpy) in position 4, [Ru(bpyBr)(2)(acac)](PF(6)) (2; bpyBr = 4-Bromo-2,2'-bipyridine, acac = 2,4-pentanedionate ion) and [Ru(bpyOH)(2)(acac)](PF(6)) (3; bpyOH = 4-[2-methyl-3-butyn-2-ol]-2,2'-bipyridine) were prepared as candidates for building blocks. The (1)H NMR, (13)C NMR, UV-Vis, electrochemistry and FAB mass spectral data of these complexes are presented. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.057
• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 [RuCl2(4-bromo-2,2'-bipyridine)2] 、 乙酰丙酮 在 KOH 作用下， 以 H₂O 为溶剂， 以90.6%的产率得到[Ru(bpyBr)2(acac)][PF6]
  参考文献：
  名称：

  Synthesis and characterization of β-diketonato ruthenium(II) complexes with two 4-bromo or protected 4-ethynyl-2,2′-bipyridine ligands

  摘要：

  Two new mononuclear mixed-ligand ruthenium(II) complexes with acetylacetonate ion (2,4-pentanedionate, acac) and functionalized bipyridine (bpy) in position 4, [Ru(bpyBr)(2)(acac)](PF(6)) (2; bpyBr = 4-Bromo-2,2'-bipyridine, acac = 2,4-pentanedionate ion) and [Ru(bpyOH)(2)(acac)](PF(6)) (3; bpyOH = 4-[2-methyl-3-butyn-2-ol]-2,2'-bipyridine) were prepared as candidates for building blocks. The (1)H NMR, (13)C NMR, UV-Vis, electrochemistry and FAB mass spectral data of these complexes are presented. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.057