[GaBr3(pyrazine)]n | 959771-82-5

• 英文名称: [GaBr3(pyrazine)]n
• 英文别名: [GaBr3(pyz)]n
• CAS: 959771-82-5
• 化学式: C₄H₄Br₃GaN₂
• 分子量: 389.524
• InChiKey: GOWVEIJNQFFXDQ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡嗪 、 三溴化镓 以 四氢呋喃 为溶剂， 以85.1%的产率得到[GaBr3(pyrazine)]n
  参考文献：
  名称：

  From gallium to thallium: Group 13 one-dimensional polymers

  摘要：

  The reactions of EX3 (E = Ga, In, Tl, X = Br or Cl) with pyrazine and pyrazine, 2-carboxylic acid (pyzea-H) affords a series of one-dimensional ladder polymers, [EX3(PYZ)](infinity) (E = Ga, In, Tl, X = Cl, Br) and the zigzag polymer [InBr2(OH2)(2)(pyzca)](infinity). These polymers are prepared in high yield through a facile synthesis. The structures of each were characterized in the solid state by single crystal X-ray analysis, infrared spectroscopy and where possible NMR. Experimental results reveal how stability of the one-dimensional polymer increases from gallium to thallium, from the air-sensitive gallium polymer to the aqueous preparation and air-stable products of indium and thallium. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.03.048