(2-(N,N-dimethylaminomethyl)phenyl)(n-butyl)Sn(ferroceneacetate)2 | 1308890-28-9

• 英文名称: (2-(N,N-dimethylaminomethyl)phenyl)(n-butyl)Sn(ferroceneacetate)2
• 英文别名: (2-(N,N-dimethylaminomethyl)phenyl)(n-Bu)Sn(O2CCH2Fc)2
• CAS: 1308890-28-9
• 化学式: C₃₇H₄₃Fe₂NO₄Sn
• 分子量: 796.157
• InChiKey: QAKBUKGLWMPOJC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二茂铁基乙酸 、 (2-(N,N-dimethylaminomethyl)phenyl)(n-Bu)SnCl₂ 在 potassium tert-butoxide 作用下， 以 四氢呋喃 为溶剂， 以58%的产率得到(2-(N,N-dimethylaminomethyl)phenyl)(n-butyl)Sn(ferroceneacetate)2
  参考文献：
  名称：

  Synthesis, structural characterization and electrochemistry of C,N-chelated organotin(IV) dicarboxylates with ferrocenyl substituents

  摘要：

  A set of C,N-chelated organotin(IV) ferrocenecarboxylates, [L-CN(n-Bu)Sn(O(2)CFc)(2)] (1), [(L-CN)(2)Sn(O(2)CFc)(2)] (2), [L-CN(n-Bu)Sn(O(2)CCH(2)Fc)(2)] (3), [L-CN(n-Bu)Sn(O(2)CCH(2)CH(2)Fc)(2)] (4), [L-CN(n-Bu)Sn(O2CCH=CHFc)(2)] (5), [L-CN(n-Bu)Sn(O(2)CfcPPh(2))(2)] (6), [(L-CN)(2)Sn(O(2)CfcPPh(2))(2)] (7), and [L-CN(n-Bu)(2)Sn(O(2)CFc)] (8) (L-CN = 2-(N, N-dimethylaminomethyl)phenyl, Fc = ferrocenyl and fc = ferrocene-1,1'-diyl) has been synthesized by metathesis of the respective organotin(IV) halides and carboxylate potassium salts and characterized by multinuclear NMR and IR spectroscopy. The spectral data indicated that the tin atoms in diorganotin(IV) dicarboxylates bearing one C,N-chelating ligand (1 and 3-6) are seven-coordinated with a distorted pentagonal bipyramidal environment around the tin constituted by the n-butyl group, the chelating L-CN ligand and bidentate carboxylate. Compounds 2 and 7 possessing two chelating L-CN ligands comprise octahedrally coordinated tin atoms and monodentate carboxylate donors, whereas compound 8 assumes a distorted trigonal bipyramidal geometry around tin with the carboxylate binding in unidentate fashion. The solid state structures determined for 1 center dot C6D6 and 2 by single-crystal X-ray diffraction analysis are in agreement with spectroscopic data. Compounds 1, 3-5, and 8 were further studied by electrochemical methods. Whereas the oxidations of ferrocene units in bis(carboxylate) 2 and monocarboxylate 8 proceed in single steps, compound 1 undergoes two closely spaced one-electron redox waves due to two independently oxidized ferrocenyl groups. The spaced analogues of 2, compounds 3-5, again display only single waves corresponding to two-electron exchanged. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.02.005