[(p-cymene)Ru(ethylenediamine)(SSBz)](PF6) | 1251195-05-7

• 英文名称: [(p-cymene)Ru(ethylenediamine)(SSBz)](PF6)
• CAS: 1251195-05-7
• 化学式: C₂₇H₂₉N₂RuS₂*F₆P
• 分子量: 691.707
• InChiKey: AIIHQRRQJNSKKL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1-methyl-4-propan-2-ylbenzene;oxido-oxo-phenyl-sulfanylidene-λ6-sulfane;2-pyridin-2-ylpyridine;ruthenium(2+);hexafluorophosphate 、 sodium benzylmercaptide 以 甲醇 、 二甲基亚砜 为溶剂， 生成 [(p-cymene)Ru(ethylenediamine)(SSBz)](PF6)
  参考文献：
  名称：

  An Alternate Route to Disulfanido Complexes by Nucleophilic Attack of Thiolates on Ruthenium-Bound Thiosulfonato Ligands

  摘要：

  The reaction of the thiosulfonato complexes [(p-cym)Ru(bipy)(S-SO(2)R)](+) (R = Ph, p-Tol) with the thiolates R'S(-) (R' = alkyl or aryl) leads to S-S bond cleavage and to the quantitative formation of the corresponding disulfanido derivatives [(p-cym)Ru(bipy)(S-SR')]+. The aryldisulfanido complexes also react with benzyl thiolate by S-S bond cleavage to give [(p-cym)Ru(bipy)(SSCH(2)Ph)](+).

  DOI：

  10.1021/ic101795s

文献信息

• Influence of the diamine on the reactivity of thiosulfonato ruthenium complexes with hydrosulfide (HS⁻)
  作者：Erwan Galardon、Hombeline Daguet、Patrick Deschamps、Pascal Roussel、Alain Tomas、Isabelle Artaud

  DOI：10.1039/c2dt31758c

  日期：——

  We have recently reported that cationic thiosulfonato ruthenium complexes [(p-cymene)Ru(bipy)(SSO2Ar)]+ (bipy: 2-2′-bipyridine, Ar: phenyl or p-tolyl) react with thiolates (RS−, R = alkyl or aryl) by cleavage of the S–SO2 bond and formation of a new S–S bond. In this work, we report that the outcome of the reaction is different if the hydrosulfide anion (R = H) is used, the product obtained being the hydrogen(sulfido) derivative [(p-cymene)Ru(bipy)(SH)]+. The bipy ligand is crucial in this result, and its replacement by ethylenediamine leads to a different product, the trisulfido-bridged dinuclear complex [[(p-cymene)Ru(en)(S)]2S]2+. These two new species have been fully characterized, including by X-ray diffraction studies, and the two different mechanisms leading to their formation are discussed.

  我们最近报道了阳离子硫代亚磺酸钌配合物 [(p-cymene)Ru(bipy)(SSO2Ar)]+（bipy：2,2'-联吡啶，Ar：苯基或对甲基苯基）与硫醇盐（RS⁻，R = 烷基或芳基）反应，过程为S–SO2键的断裂和新S–S键的形成。在本研究中，我们报告了如果使用氢硫根离子（R = H），反应结果会有所不同，得到的产物为氢（硫化）衍生物 [(p-cymene)Ru(bipy)(SH)]+。bipy配体在这一结果中至关重要，其被乙烯二胺替代则会导致得到不同的产物，即三硫桥联的二核配合物 [[(p-cymene)Ru(en)(S)]2S]2+。这两种新物种已被完全表征，包括X射线衍射研究，并讨论了导致其形成的两种不同机制。