[CH((CCH2)(CMe)(2,6-(i-Pr)2C6H3N)2)SiH](OC(CH2)C5H4)Fe(C5H5)] | 1313053-33-6

• 英文名称: [CH((CCH2)(CMe)(2,6-(i-Pr)2C6H3N)2)SiH](OC(CH2)C5H4)Fe(C5H5)]
• CAS: 1313053-33-6
• 化学式: C₄₁H₅₂FeN₂OSi
• 分子量: 672.809
• InChiKey: IJXQUIXUPSJJJI-ZXYSCAFTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,3-bis-(2,6-diisopropyl-phenyl)-6-methyl-4-methylene-1,2,3,4-tetrahydro-[1,3,2]diazasiline 、 乙酰基二茂铁 以 正己烷 为溶剂， 以72%的产率得到[CH((CCH2)(CMe)(2,6-(i-Pr)2C6H3N)2)SiH](OC(CH2)C5H4)Fe(C5H5)]
  参考文献：
  名称：

  Reactions of StableN-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone

  摘要：

  The reactions of L [PhC(NtBu)(2)SiCl] and L' [CH{(C=CH2)(CMe)(2,6-iPr(2)C(6)H(3)N)(2)}Si] with monoketones and quinone have been examined. The reaction of L with 2-adamantanone furnishes a [1 + 2]-cycloaddition product 1, whereas with 3,5-di-tert-butyl-o-benzoquinone leads to the [1 + 4]-ycloaddition product 2. The treatment of L' with 3,5-di-tert-butyl-o-benzoquinone gives [1 + 4]-cycloaddition product 3, and the reaction with acylferrocene yields compound 4. Compounds 1-4 were characterized by single crystal X-ray structural analysis, NMR spectroscopy, EI-MS spectrometry, and elemental analysis.

  DOI：

  10.1021/om200388a