bis(8-aminoquinoline)tetrakis(2-nitrobenzoate)diaquadizinc(II) | 1044275-23-1

• 英文名称: bis(8-aminoquinoline)tetrakis(2-nitrobenzoate)diaquadizinc(II)
• CAS: 1044275-23-1
• 化学式: C₄₆H₃₆N₈O₁₈Zn₂
• 分子量: 1119.61
• InChiKey: VTVREHMGERSLDW-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  8-氨基喹啉 、 邻硝基苯甲酸 、 水 、 zinc(II) acetate dihydrate 以 甲醇 为溶剂， 以82%的产率得到bis(8-aminoquinoline)tetrakis(2-nitrobenzoate)diaquadizinc(II)
  参考文献：
  名称：

  Steric effects in controlling co-ordination environment in zinc 2-nitrobenzoate complexes

  摘要：

  A dinuclear zinc complex having exclusive bis(unidentate) carboxylato co-ordination mode is synthesized through two-step reactions, involving solid phase reaction followed by solution reaction. The formation of such dinuclear species is governed by the ligand under consideration. For example, 2-nitrobenzoate zinc complex having 1,10-phenanthroline is mononuclear whereas a similar complex with 8-aminoquinoline is dinuclear having bis(unidentate) carboxylato co-ordination mode. The reasons for the formation such complex is explained on the basis of the distance of separation of uncoordinated oxygen atoms of the carboxylate oxygen of mononuclear and dinuclear complexes. Zinc 2-nitrobenzoate complexes having 2,2'-bipyridine is mononuclear but with 2-aminopyrimidine has a dinuclear paddle wheel structure. Solution phase reaction of 2-nitrobenzoic acid with zinc(II)acetate in the presence of 8-aminoquinoline gives bis-(8-aminoquinoline)zinc(II) 2-nitrobenzoate. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.01.044