Ru(H)(Cl)(CO)(DCPB)(PPh₃) | 468082-88-4

• 英文名称: Ru(H)(Cl)(CO)(DCPB)(PPh₃)
• CAS: 468082-88-4
• 化学式: C₄₇H₆₈ClOP₃Ru
• 分子量: 878.501
• InChiKey: YFLJZEANNOQWCU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 氢气 在 NaBPh₄ 作用下， 以 四氢呋喃 为溶剂， 以55%的产率得到Ru(H)(Cl)(CO)(DCPB)(PPh₃)
  参考文献：
  名称：

  Reactions of hydrogen with ruthenium and osmium complexes containing tridentate ligands Cy2PCH2CH(CH2)2PCy2 and 2,6-(Ph2PCH2)2C6H3

  摘要：

  Reaction of cis-1,4-dichlorobut-2-ene with dicyclohexylphosphine in the presence of KI in acetone produces [cis-Cy2PHCH2CH = CHCH2PHCy2]I-2 which is converted to cis-Cy2PCH2CH = CHCH2PCy2 on treatment with NaOH. Reactions of cis-Cy2PCH2CH = CHCH2PCy2 With MHCl(CO)(PPh3)(3) (M = Ru, Os) yield MHCl(CO)(PPh3)(Cy2PCH2CH = CHCH2PCy2). The ruthenium complex RuCl(CO)(PPh3)(Cy2PCH2CH(CH2)(2)PCy2) is obtained by refluxing RuHCl(CO)(PPh3)(Cy2PCH2CH = CHCH2PCy2) in methanol-CH2Cl2. Reaction of RuCl(CO)(PPh3)(Cy2PCH2CH(CH2)(2)PCy2) with H-2 in the presence of NaBPh4 produces RuHCl(CO)(PPh3)(Cy-P(CH2)(4)PCy2). Reaction of OsCl(PPh3)(2,6-(Ph2PCH2)(2)C6H3) with H-3 produces OsCl(H...H)(PPh3)(2,6-(Ph2PCH2)(2)C6H3) which contains an elongated dihydrogen ligand. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00750-8

文献信息

• Ruthenium‐Catalyzed Coupling Reactions of CO ₂ with C ₂ H ₄ and Hydrosilanes towards Silyl Esters
  作者：Kana Kunihiro、Svetlana Heyte、Sébastien Paul、Thierry Roisnel、Jean‐François Carpentier、Evgueni Kirillov

  DOI：10.1002/chem.202005083

  日期：2021.2.24

  A series of in situ‐prepared catalytic systems incorporating RuII precursors and bidentate phosphine ligands has been probed in the reductive carboxylation of ethylene in the presence of triethylsilane as reductant. The catalytic production of propionate and acrylate silyl esters was evidenced by high‐throughput screening (HTS) and implemented in batch reactor techniques. The most promising catalyst

  在三乙基硅烷作为还原剂的情况下，在乙烯的还原羧化反应中，探索了一系列结合Ru II前体和双齿膦配体的原位催化体系。高通量筛选（HTS）证明了丙酸酯和丙烯酸甲硅烷基酯的催化生产，并在间歇反应器技术中实施。鉴定出最有希望的催化剂体系是由Ru（H）（Cl）（CO）（PPh 3）3和1,4-双（二环己基膦基）丁烷（DCPB）或1,1'-二茂铁-二基-双（环己基膦）制成）（DCPF）。注意到水对丙烯酸酯/丙酸酯选择性的显着影响。周转数[mol mol（Ru）-1]多达16为丙烯酸酯和高达68为丙酸酯相对温和的条件下达到（20巴，100℃，0.5摩尔％的Ru，40摩尔％H 2 ö与HSiEt 3）。讨论了可能的机制。