(η6-C6H6)V(1+) | 102307-49-3

• 英文名称: (η6-C6H6)V(1+)
• 英文别名: [V(η-6-benzene)](1+)；vanadium(1+)-(benzene)；V(benzene)(1+)
• CAS: 102307-49-3
• 化学式: C₆H₆V
• 分子量: 129.055
• InChiKey: HMJULFGTXKYLGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η6-C6H6)V(1+) 、 一氧化碳 生成
  参考文献：
  名称：

  A soft-landing experiment on organometallic cluster ions: infrared spectroscopy of V(benzene)2 in Ar matrix

  摘要：

  Vanadium (V)benzene cluster ions, produced by laser ablation with reaction toward benzene vapor, were size-selected and deposited into a low-temperature Ar matrix. Infrared spectrum of V-1(benzene)(2) in the Ar matrix was measured after one-hour deposition with the deposition energy of 20 eV. The spectrum was in agreement with both the reported spectrum and our theoretical calculations, showing that (1) V-1(benzene)(2), prepared in the gas-phase reaction, takes a sandwich structure and that (2) the ions were soft-landed onto the Ar matrix and were neutralized by charge transfer from a metal substrate without fragmentation. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(00)01450-0
• 作为产物：
  描述：

  钒 、 苯 以 neat (no solvent) 为溶剂， 生成 、 、 、 (η6-C6H6)V(1+) 、 bis(η(6)-benzene)vanadium
  参考文献：
  名称：

  A soft-landing experiment on organometallic cluster ions: infrared spectroscopy of V(benzene)2 in Ar matrix

  摘要：

  Vanadium (V)benzene cluster ions, produced by laser ablation with reaction toward benzene vapor, were size-selected and deposited into a low-temperature Ar matrix. Infrared spectrum of V-1(benzene)(2) in the Ar matrix was measured after one-hour deposition with the deposition energy of 20 eV. The spectrum was in agreement with both the reported spectrum and our theoretical calculations, showing that (1) V-1(benzene)(2), prepared in the gas-phase reaction, takes a sandwich structure and that (2) the ions were soft-landed onto the Ar matrix and were neutralized by charge transfer from a metal substrate without fragmentation. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0009-2614(00)01450-0