[1,3-(trans-RuCl(bis(diphenylphosphino)ethane)2NC)C6H4(CN)][PF6] | 958870-86-5

• 英文名称: [1,3-(trans-RuCl(bis(diphenylphosphino)ethane)2NC)C6H4(CN)][PF6]
• 英文别名: [1,3-(trans-RuCl(dppe)2NC)C6H4(CN)][PF6]
• CAS: 958870-86-5
• 化学式: C₆₀H₅₂ClN₂P₄Ru*F₆P
• 分子量: 1206.47
• InChiKey: HBSLCNNSGOEWSE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  thallium(I) hexafluorophosphate 、 [1,2-bis(diphenylphosphino)ethane](η5-cyclopentadienyl)iron(II) iodide 、 [1,3-(trans-RuCl(bis(diphenylphosphino)ethane)2NC)C6H4(CN)][PF6] 以 二氯甲烷 为溶剂， 以48%的产率得到[1,3-(trans-RuCl(1,2-bis(diphenylphosphino)ethane)2NC)C6H4(CNFeCp(1,2-bis(diphenylphosphino)ethane))][PF6]2
  参考文献：
  名称：

  Syntheses and characterization of novel ruthenium complexes based on 1,3-dicyanobenzene

  摘要：

  The syntheses and full characterization of novel ruthenium complexes based on 1,3-dicyanobenzene are described. Crystal structures are reported for both [1,3-(cis-RuCl(P(CH3)(3))(4)N C)(2)C6H4][PF6](2) (leis) and [1,3-(trans-RuCI(dppe)(2)N=C)(2)C6H4][H2PO4](2) (3'). Ligand substitution in the homobimetallic complex (3) leads easily to the monometallic analogue, [1,3-(trans-RuCl(dppe)(2)N C)C6H4(C N)][PF6] (4). A heterobimetallic complex, [1,3-(trans-RuCI(dppe)(2)N C)C6H4(C N-FeCp(dppe))][PF6](2) (5), of satisfactory purity is also obtained. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.08.012
• 作为产物：
  描述：

  间苯二甲腈 、 [1,3-(trans-RuCl(bis(diphenylphosphino)ethane)2NC)2C6H4][PF6]2 以 1,2-二氯乙烷 为溶剂， 以83%的产率得到[1,3-(trans-RuCl(bis(diphenylphosphino)ethane)2NC)C6H4(CN)][PF6]
  参考文献：
  名称：

  Syntheses and characterization of novel ruthenium complexes based on 1,3-dicyanobenzene

  摘要：

  The syntheses and full characterization of novel ruthenium complexes based on 1,3-dicyanobenzene are described. Crystal structures are reported for both [1,3-(cis-RuCl(P(CH3)(3))(4)N C)(2)C6H4][PF6](2) (leis) and [1,3-(trans-RuCI(dppe)(2)N=C)(2)C6H4][H2PO4](2) (3'). Ligand substitution in the homobimetallic complex (3) leads easily to the monometallic analogue, [1,3-(trans-RuCl(dppe)(2)N C)C6H4(C N)][PF6] (4). A heterobimetallic complex, [1,3-(trans-RuCI(dppe)(2)N C)C6H4(C N-FeCp(dppe))][PF6](2) (5), of satisfactory purity is also obtained. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.08.012