| 1586046-70-9

• CAS: 1586046-70-9
• 化学式: C₇₆H₇₁BF₂GaN₁₁O
• 分子量: 1273.0
• InChiKey: HBBLDWGYFMHVAP-OGVDNQKDSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  8-(4-(N-(prop-2-yn-1-yl)benzamide))-2,8-diethyl-1,3,7,9-tetramethyl-BODIPY 、 10-(4-azidomethylphenyl)-5,15-dimesitylcorrolegallium(III)(pyridine) 在 copper(l) iodide 、 N,N-二异丙基乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以96%的产率得到
  参考文献：
  名称：

  Slow and Fast Singlet Energy Transfers in BODIPY-gallium(III)corrole Dyads Linked by Flexible Chains

  摘要：

  Red (no styryl), green (monostyryl), and blue (distyryl) BODIPY-gallium(III) (BODIPY = boron-dipyrromethene) corrole dyads have been prepared in high yields using click chemistry, and their photophysical properties are reported. An original and efficient control of the direction of the singlet energy transfers is reported, going either from BODIPY to the gallium-corrole units or from gallium-corroles to BODIPY, depending upon the nature of the substitution on BODIPY. In one case (green), both directions are possible. The mechanism for the energy transfers is interpreted by means of through-space Forster resonance energy transfer (FRET).

  DOI：

  10.1021/ic402798f