Reactivity of Mo(PMe3)5H2 towards catecholborane: synthesis and structure of Mo(PMe3)4(η2-H2BCat)H
摘要:
Mo(PMe3)(5)H-2 reacts with catecholborane (CatBH) to give Mo (PMe3)(4)(eta(2)-H(2)BCat)H. Structural characterization by X-ray diffraction suggests that the complex is best represented as a borohydride complex, as opposed to a boryl-hydride derivative Mo(PMe3)(4)(BCat)H-3. (C) 2000 Elsevier Science Ltd All rights reserved.