Bz2SnCl(ACDA) | 886579-04-0

• 英文名称: Bz2SnCl(ACDA)
• 英文别名: Bz2SnCl(2-amino-1-cyclopentene-1-carbodithioic acid(1-))
• CAS: 886579-04-0
• 化学式: C₂₀H₂₂ClNS₂Sn
• 分子量: 494.696
• InChiKey: DLUZKUIMZABTOP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-氨基-1-环戊烯-1-二硫代甲酸 、 二氯-二(苯基甲基)锡烷 以 甲醇 为溶剂， 以88%的产率得到Bz2SnCl(ACDA)
  参考文献：
  名称：

  Synthesis and crystal structures of new complexes of di- and tribenzyltin 2-amino-1-cyclopentene-1-carbodithioates

  摘要：

  Treatment of dibenzyltin dichloride with 1 equiv. of 2-amino-1-cyclopentene-1-carbodithioic acid (ACDA) gave Bz(2)SnCl(ACDA) (1) that contains five coordinate tin. Reaction of 2 equiv. of ammonium 2-amino-1-cyclopentene-1-carbodithioic acid (AACD) with Bz(2)SnCl(2) and then recrystallization from THF produced Bz(2)Sn(ACDA)(2)center dot THF 2 in which the coordination geometry around the Sn is highly distorted from octahedral. Bz(3)Sn(ACDA) (3) was obtained from reaction of BZ(3)SnCl with 1 equiv. of AACD. The crystal structure of 3 indicates a Sn-S' interaction [3.0823(5) angstrom] that distorts the tin coordination geometry from that of an ideal tetrahedron. In 1-3 the tin atom is also coordinated to one carbon atom of each benzyl group. The products were characterized by IR and NMR (H-1, C-13, Sn-119) spectroscopy and elemental analysis. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.11.060