| 398147-20-1

• CAS: 398147-20-1
• 化学式: C₂₅H₂₉O₁₂P₂Si₂W₂*K
• 分子量: 1046.41
• InChiKey: UPIPQQCZWBRKFY-TWXTWERMSA-N

反应信息

• 作为反应物：
  描述：

  、 溴甲苯 以 四氢呋喃 为溶剂， 以46%的产率得到[1-benzyl-2-(2-ethoxycarbonylethyl)-3,6-bis(trimethylsilyl)-1,2-dihydro-1,2-diphosphinine]decacarbonylditungsten
  参考文献：
  名称：

  Investigations of the Synthesis of 1,2-Diphosphinines

  摘要：

  Several 1,2-disubstituted 3,6-bis(trimethylsilyl)-1,2-dihydro-1,2-diphosphinine complexes were prepared in a series of reactions starting from the palladium-catalyzed head-to-head dimerization of a 1-(2-ethoxycarbonylethyl)-2-trimethylsilylphosphirene W(CO)(5)-complex. The P-CH2CH2CO2Et bonds were cleaved by (BuOK)-Bu-t in THF to give the corresponding P-anions. The most significant products were the PCl-P(CH2CH2CO2Et) (4), PH-P(OH) (5), and PH-P(CH2Ph) (8) complexes. The thermolysis of the P(CH2Ph)-P(CH2Ph) complex (9) led to the corresponding phosphole complex 11 by extrusion of one phosphorus unit. Apparently, the postulated aromatic 1,2-diphosphinines are able to evolve toward other products via low-energy pathways.

  DOI：

  10.1021/om010682e