[Ru(bis(pyrrole-2-carboxaldehyde)-1,2-ethylenediimine)Cl2(PPh3)(H2O)] | 742059-42-3

• 英文名称: [Ru(bis(pyrrole-2-carboxaldehyde)-1,2-ethylenediimine)Cl2(PPh3)(H2O)]
• CAS: 742059-42-3
• 化学式: C₃₀H₃₁Cl₂N₄OPRu
• 分子量: 666.552
• InChiKey: MCEZYORYAZYPFZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 N,N'-bis((1H-pyrrol-2-yl)methylene)ethane-1,2-diamine 以 四氢呋喃 为溶剂， 以64%的产率得到[Ru(bis(pyrrole-2-carboxaldehyde)-1,2-ethylenediimine)Cl2(PPh3)(H2O)]
  参考文献：
  名称：

  Synthesis, Characterization, and Catalytic Activity of Metal Schiff Base Complexes Derived from Pyrrole‐2‐carboxaldehyde

  摘要：

  Several ruthenium(II) Schiff base complexes derived from bis(pyrrole-2-carboxaldehyde)-3,4-toluenediimine, bis(pyrrole-2-carboxaldehyde)-1,2-cyclohexanediimine, bis(pyrrole-2-carboxaldehyde)-1,8-naphthalindiimine, bis(pyrrole-2-carboxaldehyde)-1,3-propylenediimine, bis(pyrrole-2-carboxaldehyde)-1,2-phenylenediimine and bis(pyrrole-2-carboxaldehyde)-ethylenediimine, and lanthanide(III) Schiff base complexes derived from N-(2-pyrrolylmethylene)-2-aminophenol were synthesized. All the complexes were characterized by analytical and spectroscopic methods. The ruthenium Schiff base complexes were found to be effective catalysts for the oxidation of primary alcohols in the presence of N-methylmorpholine-N-oxide as oxidant.

  DOI：

  10.1081/sim-120027314