Potassium trifluoromanganate(1-) | 13827-01-5

• 英文名称: Potassium trifluoromanganate(1-)
• CAS: 13827-01-5
• 化学式: F₃Mn*K
• 分子量: 151.032
• InChiKey: APQQUKGVNQQMJI-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -1.74
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Potassium trifluoromanganate(1-) 、 fluorine 以 neat (no solvent) 为溶剂， 生成 potassium pentafluoromanganate(IV)
  参考文献：
  名称：

  Rakov; Ostropikov; Khaustov, Russian Journal of Inorganic Chemistry, 1997, vol. 42, # 2, p. 149 - 153

  摘要：

  DOI：
• 作为产物：
  描述：

  锰 在 KF 作用下， 以 氢氟酸 为溶剂， 以55%的产率得到Potassium trifluoromanganate(1-)
  参考文献：
  名称：

  Electrosynthesis of transition metal fluoro complexes by the dissolution of a sacrificial metal anode

  摘要：

  A general method for the electrosynthesis of anionic fluoro complexes of transition metals has been developed by the oxidation of sacrificial metal anodes in 20% HF medium at room temperature and at an applied potential of 2-8 V. Some mixed-valent complexes, e.g. Fe2F5.2H2O and Fe2F5.7H2O, have also been obtained by the same method. K2[MnF5].H2O was obtained by subsequent electrolytic oxidation of the Mn(II) fluoro complex obtained in situ in the first step. The method is rapid and gives a good yield with high purity.

  DOI：

  10.1016/s0277-5387(00)81335-2

文献信息

• Microwave-assisted synthesis of NaMnF₃ particles with tuneable morphologies
  作者：Nan Liu、Jessica Holmes、Nicolas Bordenave、Eva Hemmer

  DOI：10.1039/d1cc04714k

  日期：——

  Here, the synthesis of sub-micron MMnF3 (M = Na or K) particles by a rapid microwave-assisted approach is reported. Adjustment of the Na+-to-Mn2+ ratio in the reaction mixture yielded tuneable morphologies, i.e., rods, ribbons, and plates. Relaxometric results indicated that poly(acrylic acid)-capped MMnF3 particles exhibited characteristic magnetic properties, which endows them with potential T1-weighted

  在这里，报告了通过快速微波辅助方法合成亚微米 MMnF 3 (M = Na 或 K) 粒子。调整反应混合物中的 Na +与 Mn 2+ 的比例产生可调节的形态，即棒状、带状和板状。松弛测量结果表明，聚（丙烯酸）封端的 MMnF 3颗粒表现出特有的磁性，这赋予它们潜在的T 1加权造影剂能力。
• Hydrothermal crystal growth of perovskite-type fluorides
  作者：Shigeyuki S¯omiya、Shin -Ichi Hirano、Masahiro Yoshimura、Kazumichi Yanagisawa

  DOI：10.1007/bf02402800

  日期：1981.3
• Hydrothermal crystal growth of mixed crystals in the KMnF3-KCoF3 system
  作者：Kazumichi Yanagisawa、Masahiro Yoshimura、Shigeyuki Somiya

  DOI：10.1007/bf00809049

  日期：1982.1
• Chakravorti; Subrahmanyam; Bandyopadhyay, Journal of the Indian Chemical Society, 1990, vol. 67, # 10, p. 835 - 836
  作者：Chakravorti、Subrahmanyam、Bandyopadhyay

  DOI：——

  日期：——
• Babel, D.; Herdtweck, E., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Babel, D.、Herdtweck, E.

  DOI：——

  日期：——