[(η5-C5H5)Fe(η5-C5H4)CHN(C6H3-2-Cl)]2 | 634922-37-5

• 英文名称: [(η5-C5H5)Fe(η5-C5H4)CHN(C6H3-2-Cl)]2
• CAS: 634922-37-5
• 化学式: C₃₄H₂₆Cl₂Fe₂N₂
• 分子量: 645.194
• InChiKey: WVDCVSWOGUXELH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η5-C5H5)Fe(η5-C5H4)CHN(C6H3-2-Cl)]2 、 mercury(II) diacetate 、 lithium chloride 以 甲醇 、 二氯甲烷 为溶剂， 以30%的产率得到[HgCl(η5-C5H5)Fe(η5-C5H3)CHN(C6H3-2-Cl]2
  参考文献：
  名称：

  Studies on cyclomercuration of bisferrocenylimines

  摘要：

  Cyclomercuration of bisferrocenylimines [(eta(5)-C5H5)Fe{(eta(5)-C5H4)-CR=N-(C6H3-2-R')}](2), (R=H, CH3; R'=H, CH3, Cl) occurred predominantly in the ortho-position of the substituted ferrocenyl ring to yield double 2-mercurated ferrocenylimines, which arise from activation of two sigma(C-sp2,C-ferrocene-H) bonds. The composition and structure of the metallocycles were characterized by elemental analysis, IR, H-1 NMR and 2D C-13{H-1}-COSY spectra, which confirmed the existence of two five-membered mercuriocycles fused with the ferrocenyl moieties. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00120-7
• 作为产物：
  描述：

  二茂铁甲醛 、 3,3′-二氯联苯胺 在 aluminum oxide 作用下， 以 甲苯 为溶剂， 以80%的产率得到[(η5-C5H5)Fe(η5-C5H4)CHN(C6H3-2-Cl)]2
  参考文献：
  名称：

  Studies on cyclomercuration of bisferrocenylimines

  摘要：

  Cyclomercuration of bisferrocenylimines [(eta(5)-C5H5)Fe{(eta(5)-C5H4)-CR=N-(C6H3-2-R')}](2), (R=H, CH3; R'=H, CH3, Cl) occurred predominantly in the ortho-position of the substituted ferrocenyl ring to yield double 2-mercurated ferrocenylimines, which arise from activation of two sigma(C-sp2,C-ferrocene-H) bonds. The composition and structure of the metallocycles were characterized by elemental analysis, IR, H-1 NMR and 2D C-13{H-1}-COSY spectra, which confirmed the existence of two five-membered mercuriocycles fused with the ferrocenyl moieties. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00120-7