(S(Fc)S(S))-2-(p-tolylsulphinyl)-ferrocenecarboxylic acid | 401627-38-1

• 英文名称: (S(Fc)S(S))-2-(p-tolylsulphinyl)-ferrocenecarboxylic acid
• CAS: 401627-38-1
• 化学式: C₁₈H₁₆FeO₃S
• 分子量: 368.236
• InChiKey: MCPVSZBKPWGCIT-ZEECNFPPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (S(Fc)S(S))-2-(p-tolylsulphinyl)-ferrocenecarboxylic acid 在 2,4-bis(4-methoxyphenyl)-1,3-dithia-2,4-diphosp... 作用下， 以 四氢呋喃 为溶剂， 以50%的产率得到(S(Fc))-2-(p-tolylsulphanyl)-ferrocenecarboxylic acid
  参考文献：
  名称：

  Synthesis and reactivity of achiral and of a novel planar chiral thioferrocenoylsilanes

  摘要：

  The reactions of thioferrocenoylsilanes with organolithium reagents, dienes and reducing agents which afford alpha -silyl sulphides, dihydrothiopyranes and alpha -silyl ferrocenyl thiols, respectively, have been investigated. alpha -Silyl sulphides were further functionalised through carbodesilylation with aldehydes. We also report the synthesis of a new planar chiral thioferrocencylsilane that gave good diastereomeric excess in the reaction with t-butyllithium, lithium lutidine and 2,3-dimethylbuta-1,3-diene. The 1,1'-bis-thioferrocenoylsilane, too unstable to be isolated, was trapped in situ with dienes. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00944-5
• 作为产物：
  描述：

  (S)-ferrocenyl-p-tolylsulfoxide 、 二氧化碳 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 以75%的产率得到(S(Fc)S(S))-2-(p-tolylsulphinyl)-ferrocenecarboxylic acid
  参考文献：
  名称：

  Synthesis and reactivity of achiral and of a novel planar chiral thioferrocenoylsilanes

  摘要：

  The reactions of thioferrocenoylsilanes with organolithium reagents, dienes and reducing agents which afford alpha -silyl sulphides, dihydrothiopyranes and alpha -silyl ferrocenyl thiols, respectively, have been investigated. alpha -Silyl sulphides were further functionalised through carbodesilylation with aldehydes. We also report the synthesis of a new planar chiral thioferrocencylsilane that gave good diastereomeric excess in the reaction with t-butyllithium, lithium lutidine and 2,3-dimethylbuta-1,3-diene. The 1,1'-bis-thioferrocenoylsilane, too unstable to be isolated, was trapped in situ with dienes. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00944-5