[Pd(phenylpyridinate)(Ph2P(o-C6H4-CH=N-tBu))](PF6) | 253789-38-7

• 英文名称: [Pd(phenylpyridinate)(Ph2P(o-C6H4-CH=N-tBu))](PF6)
• CAS: 253789-38-7
• 化学式: C₃₄H₃₂N₂PPd*F₆P
• 分子量: 750.999
• InChiKey: XKKRLJKVOMIOAJ-ANTZUWBTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 Pd2Cl2(phenylpyridinate)2 、 N-(2'-diphenylphosphinobenzylidene)-tert-butylamine 以 丙酮 为溶剂， 以85%的产率得到[Pd(phenylpyridinate)(Ph2P(o-C6H4-CH=N-tBu))](PF6)
  参考文献：
  名称：

  New cyclometalated palladium(II) complexes with iminophosphines

  摘要：

  The synthesis of new cyclometalated compounds of palladium(Il) with the mixed-donor bidentate ligands o-Ph2PC6H4-CH=NR is described. Two series of complexes [Pd(CxN)(o-Ph2PC6H4-CH=NR)][PF6] have been prepared using either azobenzene or 2-phenylpyridine as cyclometalated ligands [CxN=azobenzene (azb); R=Me (1a), Et (2a), " Pr (39), 'Pr (4a), 'Bu (5a), Ph (6a), NH-Me (7a); CxN=2-phenylpyridine (phpy); R=Me (Ib), Et (2b)," Pr (3b),'Pr (4b),'Bu (5b), Ph (6b), NK-Me (7b)]. The new complexes were characterized by partial elemental analyses and spectroscopic methods (IR, FAB,H-1 and P-31 NMR). The molecular structures of compounds 2a (monoclinic, P 2(1)/n) and Ib (monoclinic, C 2/c) have been determined by a single-crystal diffraction study. In both cases this technique revealed the relative trans configuration between the phosphorus atom and the nitrogen atom of the ortho-metalated ligand. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00229-6