[Pd(3,4-(OCH2O)C6H2CHNCH2-[3,4-(OCH2O)C6H3]-C6,N)(μ-chloro)]2 | 398477-23-1

• 英文名称: [Pd(3,4-(OCH2O)C6H2CHNCH2-[3,4-(OCH2O)C6H3]-C6,N)(μ-chloro)]2
• CAS: 398477-23-1
• 化学式: C₃₂H₂₄Cl₂N₂O₈Pd₂
• 分子量: 848.297
• InChiKey: NCPHAYMDZGBIQS-LGVDVSCCSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pd(3,4-(OCH2O)C6H2CHNCH2-[3,4-(OCH2O)C6H3]-C6,N)(μ-chloro)]2 、 Diphenyl-<3-dimethylamino-phenyl>-phosphin 以 丙酮 为溶剂， 以79%的产率得到[Pd(3,4-(OCH2O)C6H2CHNCH2-[3,4-(OCH2O)C6H3]-C6,N)(P(p-(CH3)2NC6H4)(C6H5)2)(Cl)]
  参考文献：
  名称：

  Directed regioselectivity in cyclometallated palladium(II) compounds of N-benzylidenebenzylamines. Crystal and molecular structure of [Pd{3,4-(OCH2O)C6H2C(H)NCH2[3,4-(OCH2O)C6H3]-C2,N}(μ-O2CMe)]2

  摘要：

  The reaction of the Schiff base ligand 3,4-(OCH2O)C6H3C(H)=NCH2[3,4-(OCH2O)C6H3] (a) with Pd(OAc)(2) yields two endocyclic cyclometallated compounds: [Pd{3,4-(OCH2O)C6H2C(H)=NCH2[3,4-(OCH2O)C,H,]-C2,N}(mu -O2CMe)](2) (C2,N-bonded) (1a), and [Pd{3,4-(OCH2O)C6H2C(H)=NCH2[3,4-(OCH2O)C6H3]-C6,N}(mu -O2CMe)](2) (C6,N-bonded) (1b), which may be separated by fractional crystallization. The corresponding cyclopalladated dimers with bridging chloride ligands, 2a, 2b, have been prepared by a metathesis reaction with aqueous sodium chloride. Treatment of the latter compounds with tertiary phosphines in the appropriate molar ratio gave the mono and dinuclear compounds, 3a-8a and 3b-5b, respectively. The structure of compound la has been determined by X-ray diffraction analysis. The molecular configuration is a dimeric form of the anti isomer with the cyclopalladated moieties in an 'open-book' arrangement linked by two acetate bridging ligands. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00876-2
• 作为产物：
  描述：

  [Pd(3,4-(OCH2O)C6H2CHNCH2-[3,4-(OCH2O)C6H3]-C6,N)(.mu-acetato)]2 、 sodium chloride 以 水 、 丙酮 为溶剂， 以89.4%的产率得到[Pd(3,4-(OCH2O)C6H2CHNCH2-[3,4-(OCH2O)C6H3]-C6,N)(μ-chloro)]2
  参考文献：
  名称：

  Directed regioselectivity in cyclometallated palladium(II) compounds of N-benzylidenebenzylamines. Crystal and molecular structure of [Pd{3,4-(OCH2O)C6H2C(H)NCH2[3,4-(OCH2O)C6H3]-C2,N}(μ-O2CMe)]2

  摘要：

  The reaction of the Schiff base ligand 3,4-(OCH2O)C6H3C(H)=NCH2[3,4-(OCH2O)C6H3] (a) with Pd(OAc)(2) yields two endocyclic cyclometallated compounds: [Pd{3,4-(OCH2O)C6H2C(H)=NCH2[3,4-(OCH2O)C,H,]-C2,N}(mu -O2CMe)](2) (C2,N-bonded) (1a), and [Pd{3,4-(OCH2O)C6H2C(H)=NCH2[3,4-(OCH2O)C6H3]-C6,N}(mu -O2CMe)](2) (C6,N-bonded) (1b), which may be separated by fractional crystallization. The corresponding cyclopalladated dimers with bridging chloride ligands, 2a, 2b, have been prepared by a metathesis reaction with aqueous sodium chloride. Treatment of the latter compounds with tertiary phosphines in the appropriate molar ratio gave the mono and dinuclear compounds, 3a-8a and 3b-5b, respectively. The structure of compound la has been determined by X-ray diffraction analysis. The molecular configuration is a dimeric form of the anti isomer with the cyclopalladated moieties in an 'open-book' arrangement linked by two acetate bridging ligands. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00876-2