[Mn4Tb2(μ3-O)2(2,6-bis[((2-(2-hydroxyethoxy)ethyl)imino)methyl]-4-methylphenol-2H)(acetate)8(μ3-OMe)2(H2O)2]*n-octanol | 1071961-61-9

• 英文名称: [Mn4Tb2(μ3-O)2(2,6-bis[((2-(2-hydroxyethoxy)ethyl)imino)methyl]-4-methylphenol-2H)(acetate)8(μ3-OMe)2(H2O)2]*n-octanol
• 英文别名: [Mn4Tb2(μ3-O)2(Hbeemp)2(OAc)8(μ3-OMe)2(H2O)2]*OctOH
• CAS: 1071961-61-9
• 化学式: C₈H₁₈O*C₅₂H₈₂Mn₄N₄O₃₂Tb₂
• 分子量: 1943.06
• InChiKey: UPKCLONIZVWCGJ-UUFHSABDSA-D

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  辛醇 、 2,6-二甲酰-4-甲基苯酚 、 manganese (II) acetate tetrahydrate 、 terbium(III) acetate tetrahydrate 、 二甘醇胺 在 H₂O 、 triethylamine 作用下， 以 甲醇 为溶剂， 生成 [Mn4Tb2(μ3-O)2(2,6-bis[((2-(2-hydroxyethoxy)ethyl)imino)methyl]-4-methylphenol-2H)(acetate)8(μ3-OMe)2(H2O)2]*n-octanol
  参考文献：
  名称：

  Syntheses, structures, and magnetic properties of manganese–lanthanide hexanuclear complexes

  摘要：

  Reactions of manganese acetate and lanthanide acetate with Schiff-base ligands (H(3)beemp = 2,6-bis[((2(2-hydroxyethoxy)ethyl)imino)methyl]-4-methylphenol) yielded hexanuclear clusters of [ Mn(4)(III)Ln(2)(III)(mu(3)-O)(2)(Hbeemp)(2)(OAc)(8)(mu(3)-OMe)(2)(H(2)O)(2)] center dot C(8)H(17)OH (Ln = Gd, Tb, and Y for 1, 2, and 3, respectively). Magnetic susceptibility measurements revealed that the mixed spin systems of 1 and 2 showed ferrimagnetic behavior, while antiferromagnetic interactions were operative among Mn(3+) ions in 3. Ac magnetic susceptibility measurements for 2 showed frequency dependent in-and out-of-phase signals, confirming slow magnetic relaxation of spin reorientations. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.03.096