| 148075-07-4

• CAS: 148075-07-4
• 化学式: C₂₃H₄₁FeP₃
• 分子量: 466.347
• InChiKey: WWNLFZCRAYUPKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三甲基膦 、 2,3,5,6,7,8-六亚甲基双环[2.2.2]辛烷 、 iron(II) chloride*1.5THF 在 sodium amalgam 作用下， 以 四氢呋喃 为溶剂， 以15%的产率得到
  参考文献：
  名称：

  Ein- bis dreikernige metall-π-derivate von hericen mit (Me3P)3Fe- und CpCo-fragmenten

  摘要：

  The reaction of 2,3,5,6,7,8-hexamethylidenebicyclo[2.2.2]octane (hericene, 11), whose synthesis was optimized, with solvated FeCl2 and Na/Hg in the presence of PMe3 gave [(PMe3)3Fe](hericene) (12) and anti-[(PMe3)3Fe]2(hericene) (13). Both were characterized by H-1, C-13, and P-31 NMR spectroscopy including 2D-methods. In 13 one of the two Fe(PMe3)3 Moieties proved to be fluxional whereas 12 was rigid as seen by NMR spectroscopy. Cyclic voltammetry showed that 13 may be oxidized reversibly. 11 also reacted with cobaltocene and potassium to give [CpCo](hericene) (15), anti-[CPCo]2(hericene) (16), and all-trans-[CpCo]3(hericene) (17). The identity of 15-17 was proven by H-1 and C-13 NMR spectroscopy. Cyclic voltammetry showed 17 to undergo three successive oxidations to form the cations 17+, 17(2+), and 17(3+) which split off CpCo+ more easily than 2,3-dimethylbutadiene(cyclopentadienyl)cobalt. The splitting of the oxidation potential is an indication of the interaction between the CpCo moieties of 17.

  DOI：

  10.1016/0022-328x(93)83070-c