1,4-C6H4(COMn(CO)5)2 | 17477-08-6

• 英文名称: 1,4-C6H4(COMn(CO)5)2
• CAS: 17477-08-6
• 化学式: C₁₈H₄Mn₂O₁₂
• 分子量: 522.099
• InChiKey: MYOWVWUZUJMTDD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,4-C6H4(COMn(CO)5)2 在 potassium tri-sec-butyl-borohydride 作用下， 以 四氢呋喃 为溶剂， 以61%的产率得到羰基镁
  参考文献：
  名称：

  The synthesis and reactivity of some μ-phthaloyl and μ-phenylene complexes

  摘要：

  The binuclear mu-phthaloyl compounds 1,4-C6H4(COM)2, where M = Re(CO)5, Mn(CO)5, eta-5-C5H5Fe(CO)2, eta-5-C5H5Mo(CO)3, Rh(PPh3)2Cl2 or Co(CO)3(PPh3), have been prepared and converted to the mu-phenylene compounds 1,4-C6H4M2, where M = Re(CO)5. Mn(CO)5 or eta-5-C5H5Fe(CO)2. The reactions of the mu-phthaloyl compounds with halogens, reducing agents and PPh3 are reported, as are the reactions of the mu-phenylene complexes with CO, synthesis gas, SO2, halogens and tertiary phosphines.

  DOI：

  10.1016/s0277-5387(00)83759-6
• 作为产物：
  描述：

  1,4-C6H3(Mn(CO)5)2 在 一氧化碳 作用下， 以 四氢呋喃 为溶剂， 以84%的产率得到1,4-C6H4(COMn(CO)5)2
  参考文献：
  名称：

  The synthesis and reactivity of some μ-phthaloyl and μ-phenylene complexes

  摘要：

  The binuclear mu-phthaloyl compounds 1,4-C6H4(COM)2, where M = Re(CO)5, Mn(CO)5, eta-5-C5H5Fe(CO)2, eta-5-C5H5Mo(CO)3, Rh(PPh3)2Cl2 or Co(CO)3(PPh3), have been prepared and converted to the mu-phenylene compounds 1,4-C6H4M2, where M = Re(CO)5. Mn(CO)5 or eta-5-C5H5Fe(CO)2. The reactions of the mu-phthaloyl compounds with halogens, reducing agents and PPh3 are reported, as are the reactions of the mu-phenylene complexes with CO, synthesis gas, SO2, halogens and tertiary phosphines.

  DOI：

  10.1016/s0277-5387(00)83759-6

文献信息

• Hunter, Allen D.; Szigety, Andrew B., Organometallics, 1989, vol. 8, # 11, p. 2670 - 2679
  作者：Hunter, Allen D.、Szigety, Andrew B.

  DOI：——

  日期：——