| 888960-63-2

• CAS: 888960-63-2
• 化学式: C₁₄H₂₄NRuS₂
• 分子量: 371.553
• InChiKey: KHLRYJFEUOAPHN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 以 乙腈 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Sulfur-alkylation-initiated Cp∗Ru thiyl radicals

  摘要：

  The formation of thiyl radicals from [Cp*Ru-III{(KSSS)-S-3'-tpdt}] (1A) and [Cp*Ru-III{(KSSN)-S-3-apdt}] (1B) {Cp* = eta(5)-C5Me5; tpdt = S(CH2CH2S-)(2); apdt = HN(CH2CH2S-)(2)} has been initiated by thiolate alkylation or oxidation with iodine. Subsequent electron transfer processes yielded disulfide-bridged dinuclear complexes. The mechanistic pathways of these processes will be discussed. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.03.018
• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)] 、 Bis-β-mercaptoethylamin 在 sodium methoxide 作用下， 以 四氢呋喃 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Sulfur-alkylation-initiated Cp∗Ru thiyl radicals

  摘要：

  The formation of thiyl radicals from [Cp*Ru-III{(KSSS)-S-3'-tpdt}] (1A) and [Cp*Ru-III{(KSSN)-S-3-apdt}] (1B) {Cp* = eta(5)-C5Me5; tpdt = S(CH2CH2S-)(2); apdt = HN(CH2CH2S-)(2)} has been initiated by thiolate alkylation or oxidation with iodine. Subsequent electron transfer processes yielded disulfide-bridged dinuclear complexes. The mechanistic pathways of these processes will be discussed. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.03.018