[Ru(bis(2-methylpropyl)-2,2'-bipyridine-4,4'-dicarboxylate)(2,2':4',4''-terpyridine)Cl2] | 1163714-21-3

• 英文名称: [Ru(bis(2-methylpropyl)-2,2'-bipyridine-4,4'-dicarboxylate)(2,2':4',4''-terpyridine)Cl2]
• 英文别名: [Ru(iBu2dcbpy)(tpy)Cl2]
• CAS: 1163714-21-3；1163795-95-6
• 化学式: C₃₅H₃₅Cl₂N₅O₄Ru
• 分子量: 761.67
• InChiKey: AJORHSKNRLZCJK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ru(bis(2-methylpropyl)-2,2'-bipyridine-4,4'-dicarboxylate)(2,2':4',4''-terpyridine)Cl2] 在 nitric acid 作用下， 以 甲醇 、 乙醇 为溶剂， 生成 [(Bu4N)0.5][Ru(2,2'-bipyridine-4,4'-dicarboxylate)(2,2':4',4''-terpyridine)(NCS)2]*2.5H2O
  参考文献：
  名称：

  Ruthenium Phthalocyanine-Bipyridyl Dyads as Sensitizers for Dye-Sensitized Solar Cells: Dye Coverage versus Molecular Efficiency

  摘要：

  The application of ruthenium phthalocyanine complexes as sensitizing dyes in dye-sensitized solar cells (DSCs) is explored. Four monomeric complexes are reported which vary in peripheral substitution and axial ligand anchoring groups. Sensitizing dyes containing two ruthenium centers are also presented. These dyads, which contain ruthenium phthalocyanine and bipyridyl chromophores, were prepared using a protection/deprotection strategy that allows for convenient purification. DSCs fabricated using the phthalocyanine complexes and dyads were less efficient than those incorporating a standard DSC dye. However, on the basis of the number of molecules bound to the TiO2 electrode surfaces, several of the new complexes were more efficient at pholocurrent generation. The results highlight the importance of molecular size, and thus the dye coverage of the electrode surface in the design of new sensitizing dyes.

  DOI：

  10.1021/ic802087n
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 bis(2-methylpropyl)-2,2'-bipyridine-4,4'-dicarboxylate 、 2,2,4,4-三联吡啶 以 N,N-二甲基甲酰胺 为溶剂， 以13%的产率得到[Ru(bis(2-methylpropyl)-2,2'-bipyridine-4,4'-dicarboxylate)(2,2':4',4''-terpyridine)Cl2]
  参考文献：
  名称：

  Ruthenium Phthalocyanine-Bipyridyl Dyads as Sensitizers for Dye-Sensitized Solar Cells: Dye Coverage versus Molecular Efficiency

  摘要：

  The application of ruthenium phthalocyanine complexes as sensitizing dyes in dye-sensitized solar cells (DSCs) is explored. Four monomeric complexes are reported which vary in peripheral substitution and axial ligand anchoring groups. Sensitizing dyes containing two ruthenium centers are also presented. These dyads, which contain ruthenium phthalocyanine and bipyridyl chromophores, were prepared using a protection/deprotection strategy that allows for convenient purification. DSCs fabricated using the phthalocyanine complexes and dyads were less efficient than those incorporating a standard DSC dye. However, on the basis of the number of molecules bound to the TiO2 electrode surfaces, several of the new complexes were more efficient at pholocurrent generation. The results highlight the importance of molecular size, and thus the dye coverage of the electrode surface in the design of new sensitizing dyes.

  DOI：

  10.1021/ic802087n