| 190001-00-4

• CAS: 190001-00-4
• 化学式: C₃₇H₂₄Mo₂O₁₀P₂
• 分子量: 882.419
• InChiKey: BUULVRYMKDUPFJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 t-BuOK 作用下， 以 二乙二醇二甲醚 为溶剂， 以51.6%的产率得到(2,3-bis(diphenylphosphino)propene-PP')(tetracarbonyl)Mo
  参考文献：
  名称：

  Molybdenum carbonyl complexes of di- and triphosphines: Hydrophosphination reactions of (HCCCH2PPh2) Mo(CO)5

  摘要：

  The base catalyzed hydrophosphination reactions of (HC=CCH2PPh2)Mo(CO)(5) with Ph2PH and (Ph2PH)Mo(CO)(5) give several different products as a function of reaction conditions. These products were characterized by elemental analyses, physical properties, H-1, C-13{H-1}, and P-31{H-1} NMR spectroscopy, infrared spectroscopy, and in mast cases by X-ray crystallography.

  DOI：

  10.1016/s0022-328x(96)06599-0
• 作为产物：
  描述：

  Mo(CO)5(PPh2H) 、 ((phenyl)2HCCH2P)pentacarbonylmolybdenum 在 t-BuOK 作用下， 以 四氢呋喃 为溶剂， 以31.2%的产率得到
  参考文献：
  名称：

  Molybdenum carbonyl complexes of di- and triphosphines: Hydrophosphination reactions of (HCCCH2PPh2) Mo(CO)5

  摘要：

  The base catalyzed hydrophosphination reactions of (HC=CCH2PPh2)Mo(CO)(5) with Ph2PH and (Ph2PH)Mo(CO)(5) give several different products as a function of reaction conditions. These products were characterized by elemental analyses, physical properties, H-1, C-13{H-1}, and P-31{H-1} NMR spectroscopy, infrared spectroscopy, and in mast cases by X-ray crystallography.

  DOI：

  10.1016/s0022-328x(96)06599-0