{Fe{Si(OMe)3}(CO)3(μ-dppm)Pd(η3-C3H5) | 132374-55-1

• 英文名称: {Fe{Si(OMe)3}(CO)3(μ-dppm)Pd(η3-C3H5)
• CAS: 132374-55-1
• 化学式: C₃₄H₃₆FeO₆P₂PdSi
• 分子量: 792.956
• InChiKey: OJSHZMGIVUQTLQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  {Fe{Si(OMe)3}(CO)3(μ-dppm)Pd(η3-C3H5) 、 三正丁基氢锡 以50%的产率得到{Fe{μ-Si(OMe)2(OMe)}(CO)3(μ-dppm)Pd(SnBu3)
  参考文献：
  名称：

  Braunstein, Pierre; Knorr, Michael; Piana, Hermann, Organometallics, 1991, vol. 10, # 4, p. 828 - 831

  摘要：

  DOI：
• 作为产物：
  描述：

  bis(η3-allyl-μ-chloropalladium(II)) 、 K{Fe(CO)3(Si(OMe)3)(η1-dppm)} 以 四氢呋喃 为溶剂， 以82%的产率得到{Fe{Si(OMe)3}(CO)3(μ-dppm)Pd(η3-C3H5)
  参考文献：
  名称：

  Braunstein, Pierre; Knorr, Michael; Piana, Hermann, Organometallics, 1991, vol. 10, # 4, p. 828 - 831

  摘要：

  DOI：
• 作为试剂：
  描述：

  三正丁基氢锡 在 {Fe{Si(OMe)3}(CO)3(μ-dppm)Pd(η3-C3H5) 作用下， 以 二氯甲烷 为溶剂， 生成 六正丁基二锡
  参考文献：
  名称：

  Reactivity of Heterobimetallic Alkoxysilyl and Siloxy Complexes in the Catalytic Dehydrogenative Coupling of Tin Hydrides

  摘要：

  Heterobimetallic complexes [(OC)(3)(R3Si)Fe(mu-dppm)Pd(eta(3)-allyl)] 1 (R = OMe, Me, OSiMe3, OSi(H)Me-2) and [(OC)(3)Fe{mu-Si(OR)(2)(OR)}(mu-dppm)PdCl] 6 (R = Me, SiMe3) are effective catalyst in the dehydrogenative coupling of triorganotin hydrides HSnR3' (R' = Ph, Bu-n). Although the elementary transformations during catalysis appear to take place at palladium, the function of the iron fragment is to provide the palladium center with the appropriate coordination environment through metal-metal bonding and the Si-containing ligand. Indeed, complexes 1 and 6 revealed a higher catalytic activity than mononuclear Pd catalysts. Modifications of the substituents at silicon resulted in considerable variations of the TON (turnover number) and TOF (turnover frequency) values as well as in the lifetime of the catalysts. In the case of siloxy derivatives, TON and TOF values higher than in the case of the alkoxysilyl analogs have been obtained whereas the lifetime of the catalyst is much longer for the latter. Possible mechanisms which rationalize the role of the silicon ligand are discussed. Solvent effects have also been observed. One of the key features of these systems is the retention of the bimetallic nature of the catalyst. TON and TOF higher than 2 x 10(5) and 3 x 10(7) h(-1), respectively, have been obtained in the case of (HSnBu3)-Bu-n. The catalytic activity of 1 toward the dehydropolymerization of tin dihydrides has been tested.

  DOI：

  10.1021/om970353f

文献信息

• Reactivity of heterobimetallic alkoxysilyl and siloxyl complexes in the dehydrogenative coupling of stannanes
  作者：Pierre Braunstein、Xavier Morise、Jo�l Blin

  DOI：10.1039/c39950001455

  日期：——

  Heterobimetallic iron-palladium alkoxysilyl- and siloxyl-complexes catalyse the dehydrogenative tin–tin coupling reaction; high turnover numbers are obtained, whereas modifications of the silicon-containing ligand strongly influence the efficiency of the catalyst.

  异种金属铁-钯烷氧基硅烷和硅氧烷络合物催化了脱氢锡-锡偶联反应；获得了较高的周转次数，而含硅配体的改性对催化剂的效率有很大影响。