| 202934-16-5

• CAS: 202934-16-5
• 化学式: C₁₅H₁₅BrCl₄Ru
• 分子量: 518.07
• InChiKey: FATZTHAGLRLSLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  pentamethylcyclopentadienyl-ruthenium(III) bromide 、 1-diazo-2,3,4,5-tetrachlorocyclopenta-2,4-diene 在 Zn 作用下， 以 四氢呋喃 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Coordination chemistry of perhalogenated cyclopentadienes XXII. Reaction of tetrabromodiazocyclopentadiene with some halide bridged Rh(I), Ru(II) and Ru(III) complexes. Molecular structure of [C5Br5]Rh(COD), a complex with an η1,η4-coordinated cyclopentadienyl ligand

  摘要：

  The halide bridged complexes [Cp*RuBr2](n) and [(COD)Rh(mu-X)](2) (X = Cl, Br) react with tetrabromodiazocyclopentadiene C5Br4N2 to give the pentahalocyclopentadienyl complexes Cp*Ru[C5Br5] (1a) and either [C5Br4Cl]Rh(COD) (2a) or [C5Br5]Rh(COD) (2b), respectively. Treatment of C5Cl4N2 with [Cp*RuBr](4) or [(COD)Rh(mu-Br)](2) yields the analogous complexes LnM [C5Cl4Br] (LnM = Cp*Ru (1b), (COD)Rh (2c)) in high yield. A crystal structure determination of 2b shows the cyclopentadienyl ligand in an unusual eta(1),eta(4)-bonding fashion. Crystals of 2b are orthorhombic, space group Pnma, a = 10.86(2), b = 12.841(5), c = 11.972(4) Angstrom, V = 1670(3) Angstrom(3), Z = 4, R1 = 5.81%, wR2 = 14.22%. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05882-9