[Ni2(μ2-bis(diphenylphosphine)amine)2(μ2-CNMe)(CNMe)2] | 639807-04-8

• 英文名称: [Ni2(μ2-bis(diphenylphosphine)amine)2(μ2-CNMe)(CNMe)2]
• CAS: 639807-04-8
• 化学式: C₅₄H₅₁N₅Ni₂P₄
• 分子量: 1011.31
• InChiKey: NEIDVGPDCYUUHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)nickel (0) 、 甲胩 、 N,N-双(二苯磷)胺 以 四氢呋喃 、 甲苯 为溶剂， 生成 [Ni2(μ2-bis(diphenylphosphine)amine)2(μ2-CNMe)(CNMe)2]
  参考文献：
  名称：

  Dinuclear Nickel Complexes as Catalysts for Electrochemical Reduction of Carbon Dioxide

  摘要：

  Dinuclear Ni(0) complexes [Ni-2(mu-dppa)(2)(mu-CNR)(CNR)(2)] (R = Me (1), n-Bu (2), and 2,6Me(2)C(6)H(3) (3); dppa = bis(diphenylphosphine)amine) were synthesized in good yields by reacting Ni(COD)2 with dppa and the corresponding isocyanide. The X-ray structure of complex 1 is reported. The electrochemistry and spectroelectrochemistry of each complex are also reported. Complex 2 exhibits an irreversible 1 e(-) reduction at -0.99 V vs ferrocene in its cyclic voltammogram. When the cyclic voltametry was performed in the presence of CO2, a substantial current enhancement was observed for the reduction wave. Spectroelectrochemical as well as isotope labeling studies show that 2 is singly reduced to a radical anion species that is reactive toward CO2, yielding the disproportionation products CO and CO32-. In the presence of H+ donors (residual water), reduction Of CO2 to formate is a competing process.

  DOI：

  10.1021/om0494723