[(C5H5)2ZrCl(2-allyl-6-methylphenol(-1H))] | 870821-61-7

• 英文名称: [(C5H5)2ZrCl(2-allyl-6-methylphenol(-1H))]
• CAS: 870821-61-7
• 化学式: C₂₀H₂₁ClOZr
• 分子量: 404.063
• InChiKey: LXBRDGDEEMELKP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二氯二茂锆 、 2-烯丙基-6-甲基苯酚 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以92%的产率得到[(C5H5)2ZrCl(2-allyl-6-methylphenol(-1H))]
  参考文献：
  名称：

  Ethylene polymerization behavior of monometallic complexes and metallodendrimers based on cyclopentadienyl-aryloxy titanium units

  摘要：

  Titanium-containing carbosilane dendrimers of type nG-Si[(CH2)(3)[{C6H4_ (y),(OMe)(y)}O]Ti(C5H5)Cl](x), in which phenoxy group is anchored to the dendritic skeleton in para position through eugenol or 2-allyl-2,6-dimethoxyphenol precursors, were used in ethylene polymerization. Fresh toluene solutions of these dendrimers in conjunction with MAO behaved as moderate active systems. However, their aged toluene solutions, when they were activated with MAO became highly active catalysts as result of dendrimer aggregation processes. However, when the peripheral unit are replaced by [Ti(C5Me5)Cl-2,] or [M(C5H5)(2)Cl] groups or 2-allyl-6-methylphenol are incorporated to the peryphery of a carbosilane dendrimer no aggregation was observed upon aging. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.06.041