Lu(1-(2-methoxyethyl)indenyl)2Cl | 214679-30-8

• 英文名称: Lu(1-(2-methoxyethyl)indenyl)2Cl
• CAS: 214679-30-8
• 化学式: C₂₄H₂₆ClLuO₂
• 分子量: 556.889
• InChiKey: FMYGJESQYITDJZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯化镥(III) 、 1-(2-methoxyethyl)-1H-indene 在 K 作用下， 以 四氢呋喃 为溶剂， 以50%的产率得到Lu(1-(2-methoxyethyl)indenyl)2Cl
  参考文献：
  名称：

  Chiral lanthanocene complexes with an ether-functionalized indene ligand: synthesis and structure of bis{1-(2-methoxyethyl)indenyl}lanthanocene chlorides

  摘要：

  Chiral lanthanocene chlorides (CH3OCH2CH2C9H6)(2)LnCl (Ln = Y 1, La 2, Nd 3, Gd 4, Ho 5 and Lu 6) with an ether-functionalized indenyl ligand were synthesized by the reaction of 1-(2-methoxyethylindenyl) potassium (in situ) with corresponding anhydrous lanthanide chlorides in THF. The X-ray crystal structures of four such complexes were determined and these indicated that they were unsolvated monomeric complexes with a trans arrangement of both the sidearms and indenyl rings in the solid state. This configuration also predominated in THF solution, as evidenced by NMR spectra of the diamagnetic complexes 1, 2 and 6, although some minor species of 1 and 2 did form upon dissolution. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00635-4