Zn6(μ4:η1:η2:η2:η1(C5NH4)2CO)2(syn,syn-μ2:η1:η1(CH3CO2))6(syn,anti-μ2:η1:η1(CH3CO2)2 | 374806-85-6

• 英文名称: Zn6(μ4:η1:η2:η2:η1(C5NH4)2CO)2(syn,syn-μ2:η1:η1(CH3CO2))6(syn,anti-μ2:η1:η1(CH3CO2)2
• CAS: 374806-85-6
• 化学式: C₃₈H₄₀N₄O₂₀Zn₆
• 分子量: 1265.09
• InChiKey: UHQMTLRXKXGXSD-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Zn6(μ4:η1:η2:η2:η1(C5NH4)2CO)2(syn,syn-μ2:η1:η1(CH3CO2))6(syn,anti-μ2:η1:η1(CH3CO2)2 、 N,N-二甲基甲酰胺 在 (C₂H₅)2O 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  High Nuclearity ZnII/MeCO2−/(C5NH4)2CO22− Clusters by “Depolymerization”: Conversion of a Three-Dimensional Coordination Polymer Containing Hexameric Units into Its Constituent Hexanuclear Complex

  摘要：

  The controlled cleavage of coordination polymers consisting of well-defined large units can be employed for the rational synthesis of high nuclearity clusters. This synthetic concept is demonstrated by the conversion (schematically shown) of a three-dimensional ZnII coordination polymer containing repeating hexameric units with a "twin-anchor" arrangement of the metal ions into the corresponding hexanuclear cluster by reaction with a donor solvent.

  DOI：

  10.1002/1521-3773(20010903)40:17<3211::aid-anie3211>3.0.co;2-x
• 作为产物：
  描述：

  2-二吡啶基酮 、 zinc(II) acetate dihydrate 以 乙腈 为溶剂， 以80%的产率得到Zn6(μ4:η1:η2:η2:η1(C5NH4)2CO)2(syn,syn-μ2:η1:η1(CH3CO2))6(syn,anti-μ2:η1:η1(CH3CO2)2
  参考文献：
  名称：

  High Nuclearity ZnII/MeCO2−/(C5NH4)2CO22− Clusters by “Depolymerization”: Conversion of a Three-Dimensional Coordination Polymer Containing Hexameric Units into Its Constituent Hexanuclear Complex

  摘要：

  The controlled cleavage of coordination polymers consisting of well-defined large units can be employed for the rational synthesis of high nuclearity clusters. This synthetic concept is demonstrated by the conversion (schematically shown) of a three-dimensional ZnII coordination polymer containing repeating hexameric units with a "twin-anchor" arrangement of the metal ions into the corresponding hexanuclear cluster by reaction with a donor solvent.

  DOI：

  10.1002/1521-3773(20010903)40:17<3211::aid-anie3211>3.0.co;2-x