[(η6-cymene)Ru(triphenylphosphine)(5-ferrocenyldipyrromethane(-H))][CF3SO3] | 1268492-31-4

• 英文名称: [(η6-cymene)Ru(triphenylphosphine)(5-ferrocenyldipyrromethane(-H))][CF3SO3]
• 英文别名: [(η6-C10H14)Ru(PPh3)(fcdmp)][CF3SO3]
• CAS: 1268492-31-4
• 化学式: CF₃O₃S*C₄₇H₄₄FeN₂PRu
• 分子量: 973.841
• InChiKey: PCJWJLFLLULDOC-ZYLZIDIPSA-M

反应信息

• 作为产物：
  描述：

  [(η⁶-C₁₀H₁₄)RuCl(fcdpm)] 、 silver trifluoromethanesulfonate 、 三苯基膦 以 丙酮 为溶剂， 以68%的产率得到[(η6-cymene)Ru(triphenylphosphine)(5-ferrocenyldipyrromethane(-H))][CF3SO3]
  参考文献：
  名称：

  Heteroleptic half-sandwich Ru(II), Rh(III) and Ir(III) complexes based on 5-ferrocenyldipyrromethene

  摘要：

  The synthesis and characterization of heteroleptic complexes with the formulations [(eta(6)-arene)RuCl(fcdpm)] (eta(6)-arene = C6H6, C10H14) and [(eta(5)-C5Me5)MCl(fcdpm)] (M = Rh, Ir; fcdpm = 5-ferrocenyldipyrromethene) have been reported. All the complexes have been characterized by elemental analyses, IR, H-1 NMR and electronic spectral studies. Structures of [(eta(6)-C6H6)RuCl(fcdpm)] and [(eta(6)-C10H14)RuCl(fcdpm)] have been determined crystallographically. Chelating monoanionic linkage of fcdpm to the respective metal centres has been supported by spectral and structural studies. Further, reactivity of the representative complex [(eta(6)-C10H14) RuCl(fcdpm)] with ammonium thiocyanate (NH4SCN) and triphenylphosphine (PPh3) have been examined. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.09.070