| 1242583-65-8

• CAS: 1242583-65-8
• 化学式: C₃₆H₃₄N₄O₈Zn₃
• 分子量: 846.858
• InChiKey: ZKHNALJNDXOBEJ-FOWFEXJWSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  manganese(II) perchlorate 、 N,N'-二亚水杨基-1,3-二氨基丙烷 、 N,N-二甲基甲酰胺 、 zinc(II) chloride 以 N,N-二甲基甲酰胺 为溶剂， 生成 Mn(III)(N,N'-disalicylidene-1,3-diaminopropane(2-))Cl 、
  参考文献：
  名称：

  The first Mn–Zn heterometallic dinuclear compound based on Schiff base ligand N, N′-bis(salicylidene)-1,3-diaminopropane

  摘要：

  One new heterometallic dinuclear Schiff-base complex Mn(DMF)(2)Zn(salpn)Cl-2 (1) (H(2)salpn = N,N '-bis (salicylidene)-1,3-diaminopropane) has been successfully constructed by the solvothermal reaction of Mn (ClO4)(2), ZnCl2 and H(2)salpn, and characterized by element analysis. IR spectroscopy and thermal analysis, as well as single crystal X-ray diffraction. The result reveals that compound 1 is heterodinuclear with Mn2+ and Zn2+ centers, in which they respectively present octahedral and tetrahedral coordination geometries. Each neutral molecule unit [Mn(DMF)(2)Zn(salpn)Cl-2] is further connected by four intermolecular hydrogen bonding C H.. 'Cl and two C H center dot center dot center dot O interactions from six adjacent units to form a three-dimensional supramolecular network with pcu alpha-Po 4(12). 6(3) topology. Moreover, luminescence, antifungal and antimicrobial activities of the heteronuclear compound 1 have also been investigated. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2011.04.028