2,2'-bipyridine-bis(1,2-dicarba-closo-dodecacarborane-1-thiola)toplatinum(II) | 488090-68-2

• 英文名称: 2,2'-bipyridine-bis(1,2-dicarba-closo-dodecacarborane-1-thiola)toplatinum(II)
• CAS: 488090-68-2
• 化学式: C₁₄H₃₀B₂₀N₂PtS₂
• 分子量: 701.838
• InChiKey: BTNFRJCDGJFPQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (2,2-联吡啶)二氯铂(II) 、 1-thiol-1,2-dicarba-closo-dodecaborane 在 AgO₃SCF₃ 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以72%的产率得到2,2'-bipyridine-bis(1,2-dicarba-closo-dodecacarborane-1-thiola)toplatinum(II)
  参考文献：
  名称：

  Synthesis of diimineplatinum(II) complexes containing the 1,2-dicarba-closo-dodecaborane(12)-1-thiolato ligand

  摘要：

  The novel air- and moisture-stable platinum(II)-diimine complexes containing the 1,2-dicarba-closo-dodecaborane(12)-1-thiolato ligand, [PtCl(1-S-C2B10H11)(N-N)] and [Pt(1-S-C2B10H11)(2)(N-N)] (N-N = 2,2'-bipyridine (bipy), 1,10-phenanthroline (phen)), were prepared by a facile two-step synthesis from the corresponding dichloroplatinum(II) precursors. All complexes were characterized primarily by multinuclear (H-1, B-11, C-13, and Pt-195) ID and 2D NMR spectroscopy. The structure of [Pt(1-S-C2B10H11)(2)(bipy)] was confirmed by single-crystal X-ray crystallography. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00133-6