| 183022-33-5

• CAS: 183022-33-5
• 化学式: C₁₆H₂₃MnO₄Si
• 分子量: 362.38
• InChiKey: GZZWTKBVMXTUPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 tetra-n-butylammoniumfluoride trihydrate 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Simple Organometallic Alcohols:  Synthesis of (C₅H₄OH)Mn(CO)₃ (Hydroxycymantrene) and (C₅H₄OH)W(CO)₃CH₃

  摘要：

  The reaction of tert-butyldimethylsilyl triflate with cyclopent-2-enone and 3,4-dimethylcyclopentenone, respectively, gives siloxycyclopentadienes in yields >90%, whose deprotonation and reaction with BrMn(CO)(3)(py)(2) or W(CO)(3)(CH3CN)(3)/MeI generates (CpOSi(t)BuMe(2))-Mn(CO)(3) and (CpOSi(t)BuME(2))W(CO)(3)ME. Cleavage of the organometallic silyl ether with NBu(4)F results in the formation of the previously unknown alcohols (C5H4OH)-Mn(CO)(3) and (C5H4OH)W(CO)(3)Me in 80-90% yield, from which the corresponding ethers can be synthesised.

  DOI：

  10.1021/om960611t
• 作为产物：
  描述：

  Tert-butyl-(3,4-dimethylcyclopenta-1,4-dien-1-yl)oxy-dimethylsilane 、 Manganese, bromotricarbonylbis(pyridine)- 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 以45%的产率得到
  参考文献：
  名称：

  Simple Organometallic Alcohols:  Synthesis of (C₅H₄OH)Mn(CO)₃ (Hydroxycymantrene) and (C₅H₄OH)W(CO)₃CH₃

  摘要：

  The reaction of tert-butyldimethylsilyl triflate with cyclopent-2-enone and 3,4-dimethylcyclopentenone, respectively, gives siloxycyclopentadienes in yields >90%, whose deprotonation and reaction with BrMn(CO)(3)(py)(2) or W(CO)(3)(CH3CN)(3)/MeI generates (CpOSi(t)BuMe(2))-Mn(CO)(3) and (CpOSi(t)BuME(2))W(CO)(3)ME. Cleavage of the organometallic silyl ether with NBu(4)F results in the formation of the previously unknown alcohols (C5H4OH)-Mn(CO)(3) and (C5H4OH)W(CO)(3)Me in 80-90% yield, from which the corresponding ethers can be synthesised.

  DOI：

  10.1021/om960611t