[{Zr(PPhMe2)Cp2}{cyclo-P3(PtBu2)}] | 1432036-78-6

• 英文名称: [{Zr(PPhMe2)Cp2}{cyclo-P3(PtBu2)}]
• 英文别名: [{Zr(PPhMe₂)Cp₂}{cyclo-P₃(P^tBu₂)}]
• CAS: 1432036-78-6；1432036-79-7
• 化学式: C₂₆H₃₉P₅Zr
• 分子量: 597.688
• InChiKey: QALBBCJXQBKJPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二氯二茂锆 、 (t)Bu2P-P(SiMe3)Li*2THF 、 二甲基苯基磷 以 乙二醇二甲醚 为溶剂， 反应 6.5h， 以0.03 g的产率得到[{Zr(PPhMe2)Cp2}{cyclo-P3(PtBu2)}]
  参考文献：
  名称：

  Formation of polyphosphorus ligands mediated by zirconium and hafnium complexes

  摘要：

  The reactions of R2P-P(SiMe3)Li (R = (t)3u, Pr-i, (Pr2N)-Pr-i) with [Cp2MCl2] (M = Zr, Hf), [Cp*CpaCl(2)] and [CpZrCl3] yielded polyphosphorus (mainly hexaphosphorus) compounds which can be viewed as intermediates between R2P-P(SiMe3)Li and derivatives of 1,2,3,4-tetraphosphabicyclo[1.1.0] butane. Thus R2P-P(SiMe3)Li can act as a building block for the formation of the P-2 ligand and the R2P-P(P-2) and R2P-P(P-2)P-PR2 moieties. Solid state structures of zirconium(IV) and hafnium(IV) complexes with R2P-P-2(P-2) and R2P-P(P-2)P-PR2 ligands were established by X-ray studies. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.02.046