{((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(1H-indazol-1-yl)(pyridin-2-yl)methyl)rhodium(I)}{((2,3,5,6-η)-bicylo{2.2.1}hepta-2,5-diene)(dichloro)rhodium(I)} | 153295-07-9

• 英文名称: {((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(1H-indazol-1-yl)(pyridin-2-yl)methyl)rhodium(I)}{((2,3,5,6-η)-bicylo{2.2.1}hepta-2,5-diene)(dichloro)rhodium(I)}
• CAS: 153295-07-9
• 化学式: C₇H₈Cl₂Rh*C₂₇H₂₃N₅Rh
• 分子量: 786.371
• InChiKey: GSEGOECRFSDGSN-PPJNSWHOSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [(norbornadiene)rhodium(I)chloride]2 、 bis(indazol-1-yl)pyridin-2'-ylmethane 以 丙酮 为溶剂， 以75%的产率得到{((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(1H-indazol-1-yl)(pyridin-2-yl)methyl)rhodium(I)}{((2,3,5,6-η)-bicylo{2.2.1}hepta-2,5-diene)(dichloro)rhodium(I)}
  参考文献：
  名称：

  （2,5-降冰片二烯）铑（I）与双和三（azol-1-yl）甲烷的配合物

  摘要：

  Reactions of bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]bis(mu-chloro)dirhodium, [RhCl-(NBD)]2, with bis- and tris(azolyl)methanes have been performed in methanol and acetone with 1:1 and 1:2 [RhCl(NBD)]2/ligand molar ratios. The structures of the complexes have been characterized by infrared and H-1 and C-13 NMR spectroscopy as well as X-ray diffraction analysis. Cationic species have been evidenced in the solid state while equilibria between cationic and neutral species have been established in solution.

  DOI：

  10.1021/om00013a042