(bis(oxazolinyl)pyridine)RhCl((MeCO2C)C(C6H5C)CCH2CH2O) | 443890-36-6

• 英文名称: (bis(oxazolinyl)pyridine)RhCl((MeCO2C)C(C6H5C)CCH2CH2O)
• CAS: 443890-36-6
• 化学式: C₂₅H₂₃ClN₃O₅Rh
• 分子量: 583.833
• InChiKey: SDSQXWRDDREQNN-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  (3-methoxycarbonyl)prop-2-ynyl 3-phenylprop-2-ynyl ether 、 di-μ-chloro-bis[bis(cyclo-octene)rhodium] 、 2,6-双(4,5-二氢噁唑-2-基)吡啶 以 四氢呋喃 为溶剂， 以75%的产率得到(bis(oxazolinyl)pyridine)RhCl((MeCO2C)C(C6H5C)CCH2CH2O)
  参考文献：
  名称：

  Novel Metallacycle Complexes from Bis(oxazolinyl)pyridine−Rhodium(I) Species and Diynes

  摘要：

  The reaction of [Rh(coe)(2)Cl](2) (coe = cis-cyclooctene), bis(oxazolinyl)pyridine (pybox), and diynes (O(CH(2)Cequivalent toCCO(2)Me)(2) and PhCequivalent toCCH(2)OCH(2)Cequivalent toCCO(2)Me) gave new types of metallacycle complexes, which were analyzed by X-ray crystallography and showed catalytic activity for cycloaddition of diynes and several alkynes.

  DOI：

  10.1021/om0202221